In order to investigate the seasonal variation in chemical characteristics of VOCs in the urban and suburban areas of southwest China, we used SUMMA canister sampling in Jinghong city from October 2016 to June 2017. Forty-eight VOC species concentrations were analyzed using atmospheric preconcentration gas chromatography–mass spectrometry (GC–MS), Then, regional VOC pollution characteristics, ozone formation potentials (OFP), source identity, and health risk assessments were studied. The results showed that the average concentration of total mass was 144.34 μg·m−3 in the urban area and 47.81 μg·m−3 in the suburban area. Alkanes accounted for the highest proportion of VOC groups at 38.11%, followed by olefins (36.60%) and aromatic hydrocarbons (25.28%). Propane and isoprene were the species with the highest mass concentrations in urban and suburban sampling sites. The calculation of OFP showed that the contributions of olefins and aromatic hydrocarbons were higher than those of alkanes. Through the ratio of specific species, the VOCs were mainly affected by motor vehicle exhaust emissions, fuel volatilization, vegetation emissions, and biomass combustion. Combined with the analysis of the backward trajectory model, biomass burning activities in Myanmar influenced the concentration of VOCs in Jinghong. Health risk assessments have shown that the noncarcinogenic risk and hazard index of atmospheric VOCs in Jinghong were low (less than 1). However, the value of the benzene cancer risk to the human body was higher than the safety threshold of 1 × 10−6, showing that benzene has carcinogenic risk. This study provides effective support for local governments formulating air pollution control policies.

To explore the mass concentration levels and health risks of heavy metals in the air in dense traffic environments, PM2.5 samples were collected at three sites in the city of Kunming in April and October 2013, and January and May 2014. Ten heavy metals––V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb––were analyzed by ICP–MS, and the results showed PM2.5 concentrations significantly higher in spring and winter than in summer and autumn, especially for Zn and Pb. The concentration of heavy metals on working days is significantly higher, indicating that vehicle emissions are significant contributors. An enrichment factor analysis showed that Cr, Mn, Ni, Cu, Zn, As, Cd and Pb come mainly from anthropogenic sources, while V and Co may be both anthropogenic and natural. The correlation and principal component analysis (PCA) showed that Ni, Cu, Zn, Cd and Pb mainly come from vehicles emissions and metallurgical industries; Cr and Mn, from vehicles emissions and road dust; and As, mainly from coal combustion. The health risk assessment shows that the non-carcinogenic risk thresholds of the heavy metals in PM2.5 to children and adult men and women are all less than 1. The carcinogenic risk of Cr for men and women in traffic-intensive areas exceeds 10−4, reaching 1.64 × 10−4 and 1.4 × 10−4, respectively.

The contents of potentially toxic elements (V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, and Pb) and emission characteristics of PM2.5 in soil fugitive dust (SFD) in six Yunnan cities (Baoshan, Kunming, Wenshan, Honghe, Yuxi, and Zhaotong) were investigated in this research. The results showed that the contents of Zn and Pb in PM2.5 of SFD were the highest around Honghe and Yuxi, respectively, while the contents of Mn were the highest in PM2.5 of SFD around the other four cities. The enrichment factor and correlation indicated that the potentially toxic elements’ pollution degrees of PM2.5 of SFD around Kunming, Yuxi, and Honghe were higher than those around the other three cities and that potentially toxic elements were generally affected by metal smelting activities, and in Zhaotong, were affected by coal burning activities, while in Wenshan and Baoshan were less affected by human activities. The total emission of PM2.5 of SFD in the six cities was 7705.49 t in 2018. The total emission factor of PM2.5 of SFD reached the highest level from January to May and the lowest level from July to October. The health risk assessment showed that the potentially toxic elements in PM2.5 of SFD for children in the six cities and for adults in Baoshan, Kunming, Honghe, and Zhaotong had non-carcinogenic risk (non-carcinogenic risk thresholds were greater than 1), and As contributes most to non-carcinogenic risk. The carcinogenic risk value of Cr in PM2.5 of SFD in Kunming and Zhaotong was between 1 × 10−6 and 1 × 10−4, which had a certain carcinogenic risk. More attention should be paid to alleviate health risks posed by particle-bound potentially toxic elements through SFD.

From April 2008 to July 2009, ambient measurements of 58 volatile organic compounds (VOCs), including alkanes, alkenes, and aromatics, were conducted in nine industrial cities (Shenyang, Fushun, Changchun, Jilin, Harbin, Daqing, Huludao, Anshan and Tianjin) of the Northeast Region, China (NRC). Daqing had the highest concentration of VOCs (519.68 ± 309.88 μg/m3), followed by Changchun (345.01 ± 170.52 μg/m3), Harbin (231.14 ± 46.69 μg/m3), Jilin (221.63 ± 34.32 μg/m3), Huludao (195.92 ± 103.26 μg/m3), Fushun (135.43 ± 46.01 μg/m3), Anshan (109.68 ± 23.27 μg/m3), Tianjin (104.31 ± 46.04 μg/m3), Shenyang (75.2 ± 40.09 μg/m3). Alkanes constituted the largest percentage (>40%) in concentrations of the quantified VOCs in NRC, and the exception was Tianjin dominated by aromatics (about 52.34%). Although alkanes were the most abundant VOCs at the cities, the most important VOCs contributing to ozone formation potential (OFP) were alkenes and aromatics. Changchun had the highest OFP (537.3 μg/m3), Tianjin had the lowest OFP (111.7 μg/m3). The main active species contributing to OFP in the nine cities were C2~C6 alkanes, C7~C8 aromatic hydrocarbons, individual cities (Daqing) contained n-hexane, propane and other alkane species. Correlation between individual hydrocarbons, B/T ratio and principal component analysis model (PCA) were deployed to explore the source contributions. The results showed that the source of vehicle exhausts was one of the primary sources of VOCs in all nine cities. Additionally, individual cities, such as Daqing, petrochemical industry was founded to be an important source of VOCs. The results gained from this study provided a large of useful information for better understanding the characteristics and sources of ambient VOCs incities of NRC. The non-carcinogenic risk values of the nine cities were within the safe range recognized by the U.S. Environmental Protection Agency (HQ < 1), and the lifetime carcinogenic risk values of benzene were 3.82 × 10−5~1.28 × 10−4, which were higher than the safety range specified by the US Environmental Protection Agency (R < 1.00 × 10−6). The results of risk values indicated that there was a risk of cancer in these cities.