Legal requirements for the use of refrigerants increasingly restrict the use of high-global warming potential (GWP) refrigerants. As a result, there is a growing interest in natural refrigerants and in those belonging to the hydrofluoroolefins (HFO) class, which can be used on their own or in mixtures. One of them is the R1234ze(E) refrigerant, an alternative to the R134a refrigerant as well as being a component of numerous mixtures. The knowledge of thermodynamic and transport properties of refrigerants is required for the analysis and calculation of refrigeration cycles in refrigeration, air conditioning, or heating systems. The paper presents analytical equations for calculating the properties of the R1234ze(E) refrigerant in the state of saturation and in the subcooled liquid and superheated vapour regions that do not require numerical calculations and are characterised by small deviations. The Levenberg–Marquardt algorithm—one of the methods for non-linear least squares estimation—was used to develop them. A total of 26 equations were formulated. The formulated equations were statistically verified by determining absolute and relative deviations between the values obtained from CoolProp software and calculated values. The maximum relative deviation was not higher than 1% in any of them.

Abstract. Methane hazard often occurs in hard coal mines and causes very serious accidents and can be the reason of methane or methane and coal dust explosions. History of coal mining shows that methane released from the rock mass to the longwall area was responsible for numerous mining disasters. The main source of methane are coal deposits because it is autochthonous gas and is closely related with carbonification and forming of coal deposits. Degree of methane saturation in coal deposits depends on numerous factors; mainly on presence or lack of insulating layers in cover deposit that allow or do not on degasification and easily methane outflow into surroundings. Hence in coal mining there are coal deposits that contain only low degree of methane saturation in places where is lack of insulating layers till high in methane coal deposits occurring in insulating claystones or in shales. Conducting mining works in coal deposits of high methane hazard without using of special measures to combat (ventilation, methane drainage) could be impossible. Control of methane hazard depends also on other co-occuring natural dangers for which used preventive actions eliminate methane hazard. Safety in mines excavating coal deposits saturated with methane depends on the correct estimation of methane hazard, drawn up forecasts, conducted observations, hazard control as well as undertaken prevention measures. Methane risk prevention includes identification and control methods of methane hazards as well as means of combating the explosive accumulation of methane in longwall workings. The main preventive actions in underground coal mines are: effective ventilation that prevents forming of methane fuses or placed methane accumulation in headings ventilated by airflow created by main fans and in headings with auxiliary ventilation, methane drainage using drain holes that are drilled from underground headings or from the surface, methanometry control of methane concentration in the air; location of the sensors is defined by law, additional ventilation equipment used in places of lower intensity of ventilation and places where methane is concentrated.

In the article, analysis of heat exchangers, working together with air-conditioning system, are presented. For an object with known requirement to hot and cold, air heat exchanger (ground type) is designed. For that defined system, the energy analysis of heat exchanger's energy work in yearly cycle, including a work of air treatment with full (coolingdesiccation and heating of air in the summer, heating and moisturizing in the winter) and not quite full (cooling of air in the summer, heating of air in the winter) air-conditioning are examined. Effects connected with a reduction of energy costs needed for heat treatment of air blown to the room are specified included the climatic conditions like air heating and cooling degree-hours.

Increasing emissions from mining areas and a high global warming potential of methane have caused gas management to become a vital challenge. At the same time, it provides the opportunity to obtain economic benefits. In addition, the use of combined heat and power (CHP) in the case of coalbed methane combustion enables much more efficient use of this fuel. The article analyses the possibility of electricity production using gas engines fueled with methane captured from the Budryk coal mine in Poland. The basic issue concerning the energy production from coalbed methane is the continuity of supply, which is to ensure the required amount and concentration of the gas mixture for combustion. Hence, the reliability of supply for electricity production is of key importance. The analysis included the basic characterization of both the daily and annual methane capture by the mine’s methane drainage system, as well as the development of predictive models to determine electricity production based on hourly capture and time parameters. To forecast electricity production, predictive models that are based on five parameters have been adopted. Models were prepared based on three time variables, i.e., month, day, hour, and two values from the gas drainage system-capture and concentration of the methane. For this purpose, artificial neural networks with different properties were tested. The developed models have a high value of correlation coefficient. but showed deviations concerning the very low values persisting for a short time. The study shows that electricity production forecasting is possible, but it requires data on many variables that directly affect the production capacity of the system.