A modified algorithm of background removal based on wavelet transform was developed for spectrum correction in laser-induced breakdown spectroscopy (LIBS). The optimal type of wavelet function, decomposition level and scaling factor γ were determined by the root-mean-square error of calibration (RMSEC) of the univariate regression model of the analysis element, which is considered as the optimization criteria. After background removal by this modified algorithm with RMSEC, the root-mean-square error of cross-validation (RMSECV) and the average relative error (ARE) criteria, the accuracy of quantitative analysis on chromium (Cr), vanadium (V), cuprum (Cu), and manganese (Mn) in the low alloy steel was all improved significantly. The results demonstrated that the algorithm developed is an effective pretreatment method in LIBS to significantly improve the accuracy in the quantitative analysis.

Laser keyhole welding of Ti-6Al-4V titanium alloy to AZ31B magnesium alloy was developed, and the correlations of process parameters, joint properties, and bonding mechanism were studied. The results show that the offset from the laser beam center on AZ31B side to the edge of the weld seam plays a big role in the joint properties by changing the power density irradiated at the Ti-Mg initial interface. The optimal range of the offset is 0.3 to 0.4mm in the present study. Some lamellar and granular Ti-rich mixtures are observed in the fusion zone, which is formed by intermixing melted Ti-6Al-4V with liquid AZ31B. The maximum ultimate tensile strength of the joints reaches 266 MPa. Furthermore, the fracture surface consists of scraggly remaining weld metal and smooth Ti surface. The higher the failure strength, the smaller the proportion of smooth Ti surface to whole interface is. Finally, the bonding mechanism of the interfacial layer is summarized by the morphologies and test results of fracture surfaces.