The speed of hydrogen peroxide propelled bimetallic nanorods in water is shown to be proportional to the surface area of the catalytic segment of the nanorods.
The response of an arbitrary closed quantum system to a partially coherent electric field is investigated, with a focus on the transient coherences in the system. As a model we examine, both perturbatively and numerically, the coherences induced in a three level V system. Both rapid turn-on and pulsed turn-on effects are investigated. The effect of a long and incoherent pulse is also considered, demonstrating that during the pulse the system shows a coherent response which reduces after the pulse is over. Both the pulsed scenario and the thermally broadened CW case approach a mixed state in the long time limit, with rates dictated by the adjacent level spacings and the coherence time of the light, and via a mechanism that is distinctly difference from traditional decoherence. These two excitation scenarios are also explored for a minimal "toy" model of the electronic levels in pigment protein complex PC645 by both a collisionally broadened CW laser and by a noisy pulse, where unexpectedly long transient coherence times are observed and explained.The significance of environmentally induced decoherence is noted.
We analyze a model where a closed V system is excited by two uncorrelated partially coherent fields. We use a collisionally broadened CW laser, which is a good model for an experimentally realizable partially coherent field, and show that it is possible to generate excited state coherences even if the two fields are uncorrelated. This transient coherence can be increased if splitting between the excited states is reduced relative to the radiation coherence time, τ d . For small excited state splitting, one can use this scheme to generate a long lived coherent response in the system.
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