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The surface layers were formed on titanium by plasma electrolytic oxidation (PEO) in the solutions which contain various amounts of Na(2)SiO(3)x5H(2)O, Na(3)PO(4) x12H(2)O and Ca(CH(3)COO)(2) xH(2)O. The layers were characterized using a scanning electron microscope (SEM) coupled with an energy dispersive spectrometer (EDS) and an X-ray diffractometer (XRD). The titanium/oxide surface layer interface was analyzed by X-ray photoelectron spectroscopy (XPS). The adhesive strength of the oxide layers was evaluated by the scratch-test. The bioactivity of the surface was determined by soaking in a simulated body fluid (SBF) for 7 and 30 days. The corrosion resistance was determined by electrochemical methods after 13, 181, and 733 h exposure in SBF at a temperature of 37°C. The oxide layers obtained were rough and porous and enriched with Ca, P, Si, and Na and their properties depended on the concentration of the components of the electrolyte. The results of the electrochemical examinations, after a 13 h exposure in SBF, show that the surface modification by PEO improves the corrosion resistance of titanium and it is not degraded after a long-term exposure in SBF. The electrochemical impedance spectroscopy (EIS) results indicate that the surface layers have a complex structure.

This article presents an outline of a method of planning an experiment developed by Taguchi for the optimisation of processes and as an example of its application in the optimisation of parameters of a ball-cratering method. Abrasive wear tests were performed on chosen antiwear physical vapour deposition coatings with the optimum work parameters of friction node. (The test friction node is created by the rotating ball and the immobile sample disc that is pressed against it and an abrasive slurry is drip fed into the contact zone.) Then the factor of resistance to abrasive wear was calculated based on the evaluation of their resistance to abrasive wear. The Taguchi optimisation method was used in order to devise and verify the methodology of the abrasive wear research of physical vapour deposition coatings deposited using cathodic arc evaporation on two differently prepared substrates. A series of resistance tests to abrasive wear performed using ball-cratering method was conducted in accordance with the test plan based on the Taguchi design. The variable test parameters were load, the speed of ball rotation and sliding distance. A measuring device, an optical microscope, was used to take pictures and measure the diameters of the wear traces visible in the form of craters received after the performance of tribological tests. The purpose of this research was to devise a method for testing the resistance of antiwear physical vapour deposition coatings deposited on tools and machine parts to abrasive wear (performed using the ball-cratering method) by applying the Taguchi optimisation method. The experiments were carried out using the combination of tribological test parameters based on the nine experiments (L9) using Taguchi orthogonal design with variable three test parameters of load, the speed of ball rotation and sliding distance. The results of the abrasive wear test performed using ball-cratering method on duplex and non-duplex coatings were successfully verified using the Taguchi optimisation program. Optimisation of the tribological test parameters based on the Taguchi method has been found to be very efficient and convenient for the investigation of the abrasive wear rate of the duplex and non-duplex coatings.

The aim of the work was to investigate the adhesion of AlCrN coating deposited by PVD method on TiB2/Ti composites manufactured by Spark Plasma Sintering (SPS). The composites were produced from three kinds of mixtures of powders: (1) Ti and TiB2, (2) Ti6Al4V and TiB2 and (3) Ti and B. Each of the mixtures was prepared at 50/50 wt. % ratio of components. Before the coating deposition the specimens were polished to obtain the surface roughness typically required for machine parts. For each set of specimens an individual surface preparation procedure was developed. The coating adhesion was measured using a scratch tester. The process of scratching was carried out to observe the characteristic moments of adhesive and cohesive failures. The highest critical loads were obtained for the coating deposited on composites produced from the mixture of two powders containing pure Ti and TiB2.