Abstract. The Yellow Sea, surrounded by East China and the Korea Peninsula, is a potentially important receptor for anthropogenic mercury (Hg) emissions from East Asia. However, there is little documentation about the distribution and cycle of Hg in this marine system. During the cruise covering the Yellow Sea in July 2010, gaseous elemental mercury (GEM or Hg(0)) in the atmosphere, total Hg (THg), reactive Hg (RHg) and dissolved gaseous mercury (DGM, largely Hg(0)) in the waters were measured aboard the R/V Kexue III. The mean (±SD) concentration of GEM over the entire cruise was 2.61 ± 0.50 ng m −3 (range: 1.68 to 4.34 ng m −3 ), which were generally higher than other open oceans. The spatial distribution of GEM generally reflected a clear gradient with high levels near the coast of East China and low levels in open waters, suggesting the significant atmospheric Hg outflow from East China. The mean concentration of THg in the surface waters was 1.69 ± 0.35 ng l −1 and the RHg accounted for a considerable fraction of THg (RHg: 1.08 ± 0.28 ng l −1 , %RHg/THg = 63.9%). The mean concentration of DGM in the surface waters was 63.9 ± 13.7 pg l −1 and always suggested the supersaturation of Hg(0) in the surface waters with respect to Hg(0) in the atmosphere (the degree of saturation: 7.8 ± 2.3 with a range of 3.6-14.0). The mean Hg(0) flux at the air-sea interface was estimated to be 18.3 ± 11.8 ng m −2 h −1 based on a two-layer exchange model. The high wind speed and DGM levels induced the extremely high Hg(0) emission rates. Measurements at three stations showed no clear vertical patterns of DGM, RHg and THg in the water column. Overall, the elevated Hg levels in the Yellow Sea compared with other open oceans suggested that the human activity has influenced the oceanic Hg cycle downwind of East Asia.
The superconducting (SC) phase in the phase-separated (PS) K 0.8 Fe 1.6+x Se 2 (0 ≤ x ≤ 0.15) materials is found to crystallize on Archimedean solid-like frameworks, this structural feature originate from a spinodal phase separation (SPS) at around T s ≈540K depending slightly on the Fe concentration.Two stable phases in K 0.8 Fe 1.6+x Se 2 are demonstrated to be the SC K 0.5 Fe 2 Se 2 and antiferromagnetic (AFM) K 0.8 Fe 1.6 Se 2 . The spinodal waves go along the systematic [113] direction and result in notable lamellar structure as illustrated by using the strain-field theoretical simulation. The 3-dimentional SC framework is constructed by hollow truncated octahedra similar with what discussed for Archimedean solids. Based on this structural model, we can efficiently calculate the volume fraction of SC phase in this type of PS SC materials.
Abstract. Soil pH buffering capacity (pHBC) plays a crucial role in predicting acidification rates, yet its large-scale patterns and controls are poorly understood, especially for neutral-alkaline soils. Here, we evaluated the spatial patterns and drivers of pHBC along a 3600 km long transect (1900 km sub-transect with carbonate-containing soils and 1700 km sub-transect with non-carbonate-containing soils) across northern China. Soil pHBC was greater in the carbonate-containing soils than in the non-carbonatecontaining soils. Acid addition decreased soil pH in the non-carbonate-containing soils more markedly than in the carbonate-containing soils. Within the carbonate soil subtransect, soil pHBC was positively correlated with cation exchange capacity (CEC), carbonate content and exchangeable sodium (Na) concentration, but negatively correlated with initial pH and clay content, and not correlated with soil organic carbon (SOC) content. Within the non-carbonate sub-transect, soil pHBC was positively related to initial pH, clay content, CEC and exchangeable Na concentration, but not related to SOC content. Carbonate content was the primary determinant of pHBC in the carbonate-containing soils and CEC was the main determinant of buffering capacity in the non-carbonate-containing soils. Along the transect, soil pHBC was different in regions with different aridity index. Soil pHBC was positively related to aridity index and carbonate content across the carbonate-containing soil sub-transect.Our results indicated that mechanisms controlling pHBC differ among neutral-alkaline soils of northern China, especially between carbonate-and non-carbonate-containing soils. This understanding should be incorporated into the acidification risk assessment and landscape management in a changing world.
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