In this study the feasibility of applying two kinds of mudar (Calotropis gigantea) fibers, namely bark fibers and seed fibers, as an alternative raw material for fiber-reinforced composite (FRC) is investigated. The chemical analysis of the bark and seed fibers indicates that their main components are holocellulose 76 and 69%, cellulose 57 and 49%, lignin 18 and 23%, and alkali soluble substances 17 and 15%, respectively. There are statistically significant differences in the bark and seed fiber dimensions. The bark fibers are long, with a thin wall relative to their diameter, and are therefore lightweight. The seed and bark fibers are very similar to hard- and soft-woods, in terms of chemical compositions and fiber dimensions, respectively. The mechanical properties of the mudar bark fibers are: tensile strength 381 MPa, strain at break 2.1% and Young's modulus 9.7 GPa. In general, both types of fibers have enough potential for replacing or supplementing other fibrous raw materials as reinforcing agent.
In this study the feasibility of applying two kinds of mudar (Calotropis gigantea) fibers, namely bark fibers and seed fibers, as an alternative raw material for fiber-reinforced composite (FRC) is investigated. The chemical analysis of the bark and seed fibers indicates that their main components are holocellulose 76 and 69%, cellulose 57 and 49%, lignin 18 and 23%, and alkali soluble substances 17 and 15%, respectively. There are statistically significant differences in the bark and seed fiber dimensions. The bark fibers are long, with a thin wall relative to their diameter, and are therefore lightweight. The seed and bark fibers are very similar to hard-and soft-woods, in terms of chemical compositions and fiber dimensions, respectively. The mechanical properties of the mudar bark fibers are: tensile strength 381 MPa, strain at break 2.1% and Young's modulus 9.7 GPa. In general, both types of fibers have enough potential for replacing or supplementing other fibrous raw materials as reinforcing agent.
Purpose
Mechanical and chemical properties of acrylic-melamine automotive clear coat in the presence of different percentages of well dispersed nano-layered sodium montmorillonite (Na-MMT) silicate particles were investigated. For this purpose, prepared dry clear coat film samples were subjected to the entire standard test series, usually carried out in automotive coating industry.
Design/methodology/approach
Effects of adding different percentages of nano-layered silicate on mechanical and chemical properties of acrylic-melamine automotive clear coat were investigated. To increase the compatibility of nanoclays with polymer matrix of clear coat, the surface of nanoclays was modified by benzalkonium chloride as a cationic surfactant. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used for characterization and comparison between clays before and after modification, and also after dispersion in coating. Prepared dry clear coat film samples subjected to the test series are usually carried out in automotive coating industry.
Findings
The results indicated that incorporation of 1 and 2 Wt.% of nano-layered silicate caused desired improvement in chemical and physical properties of the acrylic-melamine clear coat. Increasing the percentage of nanoclay to over 2 Wt.% caused damage in some properties such as hardness, cupping and gloss.
Research limitations/implications
All materials and methods were used in this research are industrial grade. Therefore, the introduced modified clear coat sample has potential for commercial production as an automotive clear coat.
Originality/value
As far as it was searched in the literature, effects of adding nanoclay particles on mechanical and physical properties of different clear coats, such as epoxy clear coat, have been investigated in a few researches, but in this research, common and special tests which are necessary in automotive coating industry have been ignored. In the present study for the first time, acrylic-melamine clear coat was subjected to modification using nano-clay, and also, the most common industrial test methods were used for investigation of mechanical and chemical properties.
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