In the paper several types of multilayer materials are proposed, which consist of fire-resistant woven and nonwoven materials. The developed non-woven material is a fabric made from woolen and m-aramide fibers connected in a combined way and which are components of a new multilayer material for welder's uniform. The proposed new woven materials due to their specific properties are suggested for an application as internal layers of protective clothing. Several types of fire-resistant fabrics with improved service properties are studied.