Privileged diphosphine ligands that chelate many transition metals to form stable chelation complexes are essential in a variety of catalytic processes. However, the exact identity of the catalytically active moieties remains ambiguous because the chelated metal catalysts may undergo rearrangement during catalysis to produce monophosphine–metal complexes, which are hard to isolate and evaluate the activities. By taking advantage of the isolation of two phosphorus atoms, we demonstrate here the successful construction of chiral monophosphine–Ir/Ru complexes of diphosphine ligands in covalent organic frameworks (COFs) for enantioselective hydrogenation. By condensation of the tetraaldehyde of enantiopure MeO-BIPHEP and linear aromatic diamines, we prepare two homochiral two-dimensional COFs with ABC stacking, in which the two P atoms of each diphosphine are separated and fixed far apart. Post-synthetic metalations of the COFs thus afford the single-site Ir/Ru–monophosphine catalysts, in contrast to the homogeneous chelated analogues, that demonstrated excellent catalytic and recyclable performance in the asymmetric hydrogenation of quinolines and β-ketoesters, affording up to 99.9% enantiomeric excess. Owing to the fact that the porous catalyst is capable of adsorbing and concentrating hydrogen, the catalytic reactions are promoted under ambient/medium pressure, which are typically performed under high pressure for homogeneous catalysis. This work not only shows that monophosphine–metal complexes of diphosphines can be catalytically active centers for asymmetric hydrogenation reactions but also provides a new strategy to prepare new types of privileged phosphine-based heterogeneous catalysts.

In this article, the average power handling capability (APHC) of corrugated slow-wave transmission lines (SWTLs) is investigated. Firstly, the attenuation constants of conductor and dielectric are extracted by the multiline method. Secondly, the thermal resistance of corrugated SWTLs is analyzed based on the constant-angle model. To deal with the non-uniform corrugated structure of SWTLs, the concept of average heat-spreading width (AHSW) is introduced. Finally, the APHC of the corrugated SWTL is calculated using the attenuation constant and the thermal resistance. In addition, the APHC considering the temperature-dependent resistivity of metal conductor is also presented. For validation, the APHCs of SWTLs with different geometric parameters are evaluated. The results agree well with those obtained by the commercial software.

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