In this work, MXene films incorporating cellulose nanofibers (CNFs) with a spider-web-like structure were fabricated using a facile vacuum-assisted filtration method. The CNFs significantly improved the flexibility and stability of the MXene membranes. The resulting composites functioned well as electrodes and friction layers in triboelectric nanogenerators (TENGs) when paired with either polytetrafluoroethylene (PTFE) as an electropositive material or nylon as an electronegative material. A membrane containing 20 wt % CNFs in conjunction with PTFE was extremely effective during the prolonged operation of a TENGs, generating an output voltage in excess of 1120 V at a frequency of 3.5 Hz. The surface charge density of this device was as high as 100 μC m–2. When paired with nylon, the MXene/CNF film produced a surface charge density of over 60 μC m–2. The microstructures on the rough surface of these membranes, together with the presence of −F and other polar terminations on the MXene, are responsible for the high performance of the nanocomposite. This work demonstrates that MXenes are not necessarily equivalent to PTFE within the triboelectric series and suggests that the MXene-based friction layer could greatly enhance the performance of TENGs.

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