A wire‐shaped flexible dye‐sensitized solar cell (WSF‐DSSC) without any transparent conducting oxide materials is fabricated. The cell has a helical twisting structure formed by two fiber‐like electrodes (100 μm in diameter). Due to the twisting structure, many opaque conducting materials such as metal wire can be applied. It is found that the incident‐light‐angle dependence of the cell's IV output is extremely low.

Conductive meshes are used to replace transparent conducting oxides (TCOs), which are commonly used in electrodes of dye-sensitized solar cells (DSSCs). The TCO-less flexible working electrode could be sintered under 400–500°C. A preliminary result that open-circuit voltage (VOC)=650mV, short-circuit current density (ISC)=4.5mA∕cm2, and efficiency (ηAM1.5)=1.49% (100mW∕cm2) is obtained from the liquid-type DSSC. The incident light could be dispersed uniformly inside the electrode. Testing results of the double-counterelectrode cell indicate that the transmission of electrolyte is not the rate-determining step. The dense TiO2 layer is critical in improving the cell’s performances.

Application of a hydrostatic pressure in the range of 1-650 atm boosted photoluminescence and electroluminescence of hexaphenylsilole by approximately 10 and approximately 73%, respectively, due to the suppression of intramolecular rotations and/or the increase in carrier injection, offering a helpful mechanistic insight into the intriguing phenomenon of aggregation-induced emission.