A group of novel aryltin chlorides, bromides and hydrides (Ar n SnY 4-n ) 2, Y = Cl, Br, H) have been synthesized and structurally characterized via X-ray diffraction. These compounds display noncovalent intermolecular interactions in the form of edge to face, -stacking and C-H··· interactions resulting in discrete arrangements in the solid state. The strength of these interactions and their effect on resulting structural parameters, as well as the consequence of the aromatic substituent on the type of interactions present, will be highlighted and discussed. Résumé: De nouveaux chlorures, bromures et hydrures d'arylétain (Ar n SnY 4-n ) (où Ar = o-tolyl, 2,6-xylyl, 1-naphthyl, 2-naphthyl ou p-n-butylphenyl, et Y = Cl, Br ou H) ont été synthétisés et leur structure été déterminée par cristallographie aux rayons X. Ces composées présentent des interactions intermoléculaires non covalentes de type bord-face, empilement et C-H···, qui conduisent à des arrangements distincts à l'état solide. La force de ces interactions, leur effet sur les caractéristiques structurelles qui en résultent et l'impact du substituant aromatique sur les types d'interaction présents, seront exposés et étudiés. [Traduit par la Rédaction]Mots-clés : halogénure d'arylétain, hydrure d'arylétain, motifs d'un empilement cristallin, interactions intermoléculaires, empilement .
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