Smart windows with tunable optical properties in response to external environments are being developed to reduce energy consumption of buildings. In the present study, we introduce a new type of 3D printed hydrogel with amazing flexibility and stretchability (as large as 1500%), as well as tunable optical performance controlled by surrounding temperatures. The hydrogel on a PDMS substrate shows transparent-opaque transition with high solar modulation (ΔTsol ) up to 79.332% around its lower critical solution temperature (LCST) while maintaining a high luminous transmittance (Tlum ) of 85.847% at room temperature. In addition, selective transparent-opaque transition above LCST can be achieved by patterned hydrogels which are precisely fabricated via projection micro-stereolithography (PμSL) based 3D printing technique. Our hydrogel promises great potential applications for next generation of soft smart windows.

The unidirectional fluidics underwater promises the manipulation of gas/liquid for various significant applications. Inspired by the unique stomata on the surface of hornwort stems and leaves that enable the transport and storage of oxygen underwater, we propose a bionic cell with porous membranes fabricated by the projection microstereolithography based 3D printing technique. Different Laplace forces coming from different contact angles for the respectively superhydrophilic outside and hydrophobic inside promise unidirectional fluidic performance, which stop water flowing inside of the bionic cell while exhausting gas and liquid outside of it. In addition, geometric parameters of the bionic cell make a big difference in its unique unidirectional fluidic performance. Simultaneously, the underlying mechanisms of the unidirectional penetration of liquid in our 3D printed bionic cell are theoretically revealed. Moreover, we demonstrate potential applications of our bionic cell with underwater anaerobic chemical reactions to fully apply its outstanding unidirectional fluidics underwater. Our bionic cell opens a gate for potential applications in chemical and microfluidic engineering underwater, such as the storage of flammable materials, fast solid− liquid separations, and anaerobic chemical reactions.

The key problem that hinders the water transportation performance and application of microchannels is the annoying gaslock. Realizing liquid transport without the gaslock requires a specially designed pump and a channel system, as well as the reduction of gas concentration in liquids. In nature, to eat viscous nectar with high efficiency, hummingbirds use their open geometric tongue for nectar-sucking. Inspired by hummingbirds’ tongue, we report a bionic open microchannel that discharges unwanted gas inside the microchannel from the opening without influencing its fluidic performance. The opening can also be used for extrusion of oil droplets in microchannels, indicating great potential applications in oil–water separation and chemical slow release, especially for bubble discharge in microchannels. Most significantly, a mimicked “leaf” with our bionic open microchannnels exhibits marvelous “transpiration” performance when irradiated by a laser. Our work provides a new strategy for the fabrication of open microchannels and sheds light on potential applications of multiphase phenomena in microchannels including oil–water separation, phase change heat and mass transfer, solar vapor generation, and precisely controllable drug delivery.

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Numerous structures have been functionally optimized for directional liquid transport in nature. Inspired by lush trees’ xylem that enable liquid directional transportation from rhizomes to the tip of trees, a new kind of programmable microfluidic porous matrices using projection micro‐stereolithography (PµSL) based 3D printing technique is fabricated. Structural matrices with internal superhydrophilicity and external hydrophobicity are assembled for ultra‐fast liquid rising enabled by capillary force. Moreover, the unidirectional microfluidic performance of the bionic porous matrices can be theoretically optimized by adjusting its geometric parameters. Most significantly, the successive programmable flow of liquid in a preferred direction inside the bionic porous matrices with tailored wettability is achieved, validating by a precisely printed liquid displayer and a microfluidic logic chip. The programmable and functional microfluidic matrices promise applications of patterned liquid flow, displayer, logic chip, cell screening, gas–liquid separation, and so on.