To develop an ultraefficient and reusable heterogeneous Fenton-like catalyst at a wide working pH range is a great challenge for its application in practical water treatment. We report an oxygen vacancy promoted heterogeneous Fenton-like reaction mechanism and an unprecedented ofloxacin (OFX) degradation efficiency of Cu doped FeO@FeOOH magnetic nanocomposite. Without the aid of external energy, OFX was always completely removed within 30 min at pH 3.2-9.0. Compared with FeO@FeOOH, the pseudo-first-order reaction constant was enhanced by 10 times due to Cu substitution (9.04/h vs 0.94/h). Based on the X-ray photoelectron spectroscopy (XPS), Raman analysis, and the investigation of HO decomposition, OH generation, pH effect on OFX removal and HO utilization efficiency, the new formed oxygen vacancy from in situ Fe substitution by Cu rather than promoted Fe/Fe cycle was responsible for the ultraefficiency of Cu doped FeO@FeOOH at neutral and even alkaline pHs. Moreover, the catalyst had an excellent long-term stability and could be easily recovered by magnetic separation, which would not cause secondary pollution to treated water.
Two-dimensional
(2D) materials have attracted great attention by
researchers due to their fascinating properties and promising applications.
However, the synthesis methods for few layers are usually difficult
to expand to large area applications because of their low yield. In
this paper, graphene-like MoSe2 nanosheets are successfully
and scaleable synthesized by a facile and low-cost hydrothermal method
under the synergy of PVP and graphene. The ultrathin MoSe2 nanosheets are typically 1–3 layers, which are confirmed
by HRTEM. This unique structure makes this MoSe2 electrode
material show superior activity toward the electrocatalytic hydrogen
production with a low Tafel slope about 70 mV·dec–1. Furthermore, the synthesized graphene-like MoSe2 nanosheets
had a high stability during the electrocatalytic process and we nearly
cannot find the degradation after 1000 cyclic voltammetric sweeps.
Fabricating a cost effective hydrogen evolution reaction catalyst without using precious metal elements is in crucial demand for environmentally-benign energy production. In this work, the thin and edge-rich molybdenum disulfide nanosheets, with carbon doped in the interlayers and decorated on graphene, were developed by a facile solvothermal process. The as-synthesized nanohybrids exhibited high catalytic ability for the hydrogen evolution electrochemical reaction with an onset overpotential of 0.165 mV and a Tafel slope of 46 mV dec(-1). Furthermore, the prepared nanohybrids also showed better durability and stability. Our work may lead to a potential method for in situ production of metal carbide-sulphur hybrid nanomaterials with promising applications for the hydrogen evolution reaction.
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