A novel, asymmetrically cut, channel-cut crystal was designed and manufactured with the aim to significantly reduce the beam offset change during energy scans. The improvement was verified with synchrotron radiation from an undulator source. The importance of even small, generally so far neglected, asymmetries is pointed out for high-accuracy monochromators.

Energy sustainability is critical for social activities in the human world. The quaternary compound Cu2ZnSnSe4 (CZTSe), as a promising candidate for thin-film solar cell absorption with medium-level thermoelectric performance, is of interest for the purpose of utilizing solar energy. The defect chemistry and atomic ordering in this particular compound also triggers interests in understanding its crystallographic structure as well as defects. Hereby, high energy resolution X-ray absorption spectroscopy is employed to investigate the electronic and geometric structural complexity in pristine and cobalt-doped Cu2ZnSnSe4. The occupational atomic sites of Cu are found to be mixed with the Zn atoms, forming CuZn anti-defects, which serve as a knob to tune local electronic structures. With proper doping, the band structure can be manipulated to improve the optical and thermoelectric properties of the CZTSe compounds.

Thermoelectric materials are promising for energy harvesting using waste heat. The thermal management of the thermoelectric materials are attracting scientific and technological interests. The narrow bandgap semiconductor BiAgSe2 are good...