In the complex network of chemical process systems, if a node fails, it may trigger cascading failures and affect normal operation. To enhance the ability of chemical process systems to maintain normal operation after the cascading failure, this paper presents cascading failure modelling and robustness analysis of chemical process systems based on the complex network non‐linear load capacity model. First, based on complex network theory, a complex network model of the chemical process is constructed; then, three cascading failure models are constructed using a combination of linear and non‐linear load capacity models and initial load and initial residual capacity redistribution strategies; and finally, the nodes with the maximum node degree are deliberately attacked to analyze the robustness of the chemical process system in response to cascading failure. The case study shows that the proposed models are valid and feasible, and the robustness of the chemical process system is enhanced as the load and capacity parameters are increased. By reasonably setting the initial load and adjusting the model parameters, the robustness can be effectively improved, providing a theoretical reference for improving the robustness of the actual chemical process system in response to cascading failure.

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