Kinetics and thermogravimetric analysis
of recent
Phoebe zhennan
wood (RZ)
and ancient buried
P. zhennan
wood
(ABZ) were investigated under a nitrogen atmosphere at different
heating rates of 5, 10, 15, and 20 K/min. The activation energy values
were estimated based on the Flynn–Wall–Ozawa model-free
method, and then, the Coats–Redfern model-fitting method was
used to predict the reaction mechanism. The best model of RZ for regions
1 and 2 was based on the diffusional and reaction order (second-order)
mechanism, respectively, while a diffusional (Jander equation) mechanism
is the best model for ABZ. The change in enthalpy and activation energy
of the RZ was lower than that of the ABZ at different conversion rates.
When the conversion rate was less than 0.4, the RZ may require lower
thermal decomposition reaction energy, but the overall energy of thermal
decomposition reactions and the degree of disorder was not much different.
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