Developing high performance bifunctional transition metal catalysts would be significantly beneficial for electrocatalytic oxidation of urea-rich wastewater. Herein, we synthesize a V2O3 nanosheet anchored N-doped-carbon encapsulated Ni heterostructure (Ni@C–V2O3/NF) for the reactions of urea oxidation (UOR) and hydrogen evolution (HER). Electrochemical results indicate that it exhibits small potentials of 1.32, 1.39, and 1.43 V for UOR and low overpotentials of 36, 254, and 355 mV for HER at ±10, ± 500 and ±1000 mA cm–2, respectively. It can work at 100 mA cm–2 for over 72 h as cathode and anode electrode without obvious attenuation, suggesting an outstanding durability. The reason for this behavior could be ascribed to the N-doped-carbon coating structure, the synergetic effects between Ni and V2O3, and the nano/micro nanosheets architecture self-supported on nickel foam. This work could provide a promising, inexpensive, and green method for the degradation of urea-rich wastewater and hydrogen production.

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