By using a facile one-pot synthetic route, we designed a one-dimensional hybrid nanostructure by introducing small amounts of Au species (0.9 wt %) dispersed over the amorphous tin oxide overlayers uniformly supported on coaxial carbon nanotubes as electrode materials for application in lithium ion battery. The as-synthesized CNT@SnO2−Au nanocables were characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, elemental mapping, and X-ray photoelectron spectroscopy; such hybrid nanostructure markedly improves electrode performance, especially for the rate performance. The capacities of 467 and 392 mA h g−1 were obtained at rates of 3.6 A g−1 and 7.2 A g−1, respectively.
In this paper, successful one-step chemical synthesis of Co−Pt hollow spheres with adjustable
composition was developed in an effort to explore new synthesis methods, simplify the synthesis procedure,
and improve the synthetic efficiency. In this synthesis, a direct thermolytic reduction of platinum
acetylacetonate [Pt(CH3COHCOCH3)2] and cobalt(II) acetate [Co(CH3COO)2] in refluxing ethyl glycol
was explored. In the reacting mixture, an anionic surfactant sodium dodecyl sulfate (SDS) was used as
the capping and structure-directing agent. These Co−Pt hollow spheres demonstrated enhanced
electrocatalytic activity toward methanol oxidation in comparison with Pt nanoparticles, which is crucial
for anode electrocatalysis in DMFCs.
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