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The object of study is a multi-layer composition «steel – a material with shape memory effect (SME) – wear-resistant layer» (TiNiHf - WC-Mo-Co). Ni was deposited as an adhesion layer. The sequence of functional layers deposition, their composition, thickness, structural-phase state and dispersion are determined by the operating conditions and operated by processing modes. To enhance durability and longevity it is recommended to form a layer with shape memory effect in a way that its temperature, given the increase in friction, corresponded to martensitic state and had an increased relaxation and damping capacity to inhibit cracking.

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The studies carried out show that the task of ensuring the reliability and expanding the functionality of products operating under multifactorial effects (temperature, force, deformation) can be successfully solved by functionally oriented surface composite materials with thermoelastic martensitic transformations (TMT). The authors proposed the technology of layer-by-layer synthesis of functionally-oriented composite layered materials with TMT in argon environment, implemented on patented equipment in a single technological cycle. This technology determines not only the novelty, but also the economic feasibility of technical solutions. We also suggested step-by-step methods of thermal and thermomechanical treatment of composite layered materials with TMT, which contribute to the structure stabilization while decreasing residual stress. On the basis of complex X-ray diffraction and electron microscopic studies, we determined the structural parameters of High Velocity Oxy-Fuel (HVOF) materials obtained by HVOF with subsequent thermal and thermomechanical treatment and ceramic materials ZrO2-Y2O3-CeO2-Al2O3 stabilized with Al2O3 with subsequent heat treatment. We investigated the microhardness of surface high-entropy and ceramic materials. Tests for "friction-wear" and mechanical high-cycle fatigue of steels with a composite surface laminate showed decrease in the wear rate and increase in the cyclic durability.

This paper discusses the technology, structure and functional–mechanical properties of surface layers made of high-entropy materials with a high-temperature shape memory effect, nickel (Ni)–cobalt (Co)–titanium (Ti)–zirconium (Zr)–hafnium (Hf), nickel–copper (Cu)–titanium–zirconium–hafnium and titanium–nickel–zirconium–hafnium–cobalt–copper. The developed technology and equipment for the formation of high-entropy coatings on the surface of steel products included mechanical activation of powders, high-velocity oxygen fuel (HVOF) spraying in a protective atmosphere and subsequent thermal and thermomechanical treatment. This allowed carrying out this process in a single technological cycle. The authors have developed statistical models of the formation process of highly entropic HVOF coatings in a protective atmosphere according to the criteria of adhesive strength and porosity with optimization of parameters. Based on complex X-ray diffraction and electron microscopy studies, the authors determined the structural parameters of high-entropy alloy coatings obtained by HVOF, followed by thermal and thermomechanical treatment. It was shown that all three alloys, nickel–cobalt–titanium–zirconium–hafnium, nickel–copper–titanium–zirconium–hafnium and titanium–nickel–zirconium–hafnium–cobalt–copper, which make up the surface compositions, are in an austenitic–martensitic state with a grain size of 32–120 nm. The authors performed calorimetric studies of the functional properties of the coatings. The studies showed the manifestation of austenitic–martensitic transformations. The authors also carried out tests for ‘friction wear’ and mechanical multicycle fatigue of the obtained high-entropy compositions on a steel surface.