Tidal zones providing habitats are particularly vulnerable to microplastic (MP) pollution. In this study, the effects of tidal cycles on the transport of MPs (4–6 μm polyethylene, PE1; 125 μm polyethylene, PE2; and 5–6 μm polytetrafluoroethylene, PFTE) in porous media combined with various environmental and MPs properties were systemically investigated. The results indicated that smaller substrate sizes exhibited higher retention percentages compared to those of larger substrate sizes under different tidal cycles. In terms of the size of MPs, a larger size (same density) was found to result in enhanced retention of MPs in the column. As the number of tidal cycles increased, although the transport of MPs from the substrate to the water phase was enhanced, PE1 was washed out more with the change in water level, compared to PTFE. Additionally, more MPs were retained in the column with the increase of salinity and the decrease of flow velocity under the same tidal cycles. Ultraviolet and seawater aged PE1 showed enhanced transport, while aged PTFE showed enhanced retention under the same tidal cycles. These results can help understand the MP behaviors in the shoreline environment and provide support for future cleanup and sampling in tidal zones.
The presence of plastic fragments in the environment is a growing global concern. In this study, we explored the effects of dynamic fluctuations of capillary fringe on the transport of microplastics (MPs) in the substrate combining various environmental and MP properties. Both experimental and Hydrus-2D modeling results confirmed that increasing cycles of water table fluctuation led to the rise of capillary fringe. An increase in the cycles of water table fluctuations did not significantly change the overall MP retention percentages in 0.5 mm substrate but altered the MP distribution along the column. In 1 and 2 mm substrate, the increase in cycle numbers enhanced the MP transport from substrate to the water below. In terms of the size of the MPs, more 20−25 μm polyethylene (PE2) were retained in the substrate compared to 4−6 μm polyethylene (PE1) under the same number of fluctuation cycles. High-density polytetrafluoroethylene (PTFE, 5−6 μm) exhibited higher retention percentages compared to PE1 particles. Ultraviolet aging for 60 days enhanced PE1 transport along the column, while 60 days of seawater aging did not affect PE1 transport greatly. For PTFE, ultraviolet and seawater aging enhanced its retention in the substrate. The retention percentages of both PE1 and PTFE in the column increased with the elevated ionic strength and the decrease of fluctuation velocity. This work highlights that capillary fringe fluctuation can serve as a pathway to relocate MPs to the tidal aquifer.
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