Sensitive, selective and fast detection of chemical warfare agents is necessary for anti-terrorism purposes. In our search for functional materials sensitive to dimethyl methylphosphonate (DMMP), a simulant of sarin and other toxic organophosphorus compounds, we found that zinc oxide (ZnO) modification potentially enhances the absorption of DMMP on a manganese dioxide (MnO2) surface. The adsorption behavior of DMMP was evaluated through the detection of tiny organophosphonate compounds with quartz crystal microbalance (QCM) sensors coated with ZnO-modified MnO2 nanofibers and pure MnO2 nanofibers. Experimental results indicated that the QCM sensor coated with ZnO-modified nanostructured MnO2 film exhibited much higher sensitivity and better selectivity in comparison with the one coated with pure MnO2 nanofiber film. Therefore, the DMMP sensor developed with this composite nanostructured material should possess excellent selectivity and reasonable sensitivity towards the tiny gaseous DMMP species.

Saline‐alkaline soils are wide‐spread and approximately 6.5% of the world's land area is reported as being saline and sodic. Increasing soil organic carbon (SOC) concentration and aggregate stability in saline‐alkaline soils has been challenging due to the deleterious effects of soil salinity and sodicity. To address this issue, a 2‐year filed experiment was conducted to evaluate the effects of biochar (BC), farmyard manure (FM), corn straw (CS), and sheep manure (SM) in combination of chemical fertilizer (CK) on soil aggregation and C sequestration in mildly and moderately alkaline soils in Hetao Irrigation District, China. For mildly alkaline soil, the proportion of macroaggregates (>0.25 mm) was significantly higher under FM, CS, and SM (34.6%–51.2%) compared with CK (13.2%). The mean weight diameter (MWD) and geometric mean diameter (GMD) of water‐stable aggregates significantly increased under FM, CS, and SM by an average of 172.7% and 58.7% over CK. In addition, FM, CS, and SM enhanced the distribution of organic carbon (OC) in macroaggregates (>0.25 mm) and accelerated the accumulation of particulate organic matter within macroaggregates. Treatment BC enhanced OC distribution in microaggregates (0.053–0.25 mm) and exhibited a 7.40 g kg−1 SOC content, followed by SM and FM which exhibited SOC contents of 7.10 and 6.76 g kg−1. For moderately alkaline soil, data obtained in this study showed a slight influence from organic amendments on soil aggregates and C sequestration, suggesting that the moderately alkaline soil was not as sensitive to organic amendments as the mildly alkaline soil. Overall, the results of this study demonstrated that FM and SM combined with chemical fertilizer were the top organic amendments to improve soil aggregation and C sequestration in the mildly alkaline soil but not the moderately alkaline soil over the short term.