Nanoconfined fluids (NCFs), which are confined in nanospaces, exhibit distinctive nanoscale effects, including surface effects, small-size effects, quantum effects, and others. The continuous medium hypothesis in fluid mechanics is not valid in this context because of the comparable characteristic length of spaces and molecular mean free path, and accordingly, the classical continuum theories developed for the bulk fluids usually cannot describe the mass and energy transport of NCFs. In this Perspective, we summarize the nanoscale effects on the thermodynamics, mass transport, flow dynamics, heat transfer, phase change, and energy transport of NCFs and highlight the related representative works. The applications of NCFs in the fields of membrane separation, oil and gas production, energy harvesting and storage, and biological engineering are especially indicated. Currently, the theoretical description framework of NCFs is still missing, and it is expected that this framework can be established by adopting the classical continuum theories with the consideration of nanoscale effects.

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The structure of nanoconfined fluids is particularly non-uniform owing to the wall interaction, resulting in the distinctive characteristic of thermal transport compared to bulk fluids. We present the molecular simulations on the thermal transport of water confined in nanochannels with a major investigation of its spatial distribution under the effects of wall interaction. The results show that the thermal conductivity of nanoconfined water is inhomogeneous and its layered distribution is very similar to the density profile. The layered thermal conductivity is the coupling result of inhomogeneous density and energy distributions that are generally diametrical, and their contributions to the thermal conductivity compensate with each other. However, the accumulative effect of water molecules is really dominating, resulting in a high thermal conductivity in the high-density layers with the low-energy molecules, and vice versa. Moreover, it is found that the adsorptive and repulsive interactions from solid walls have different roles in the hierarchical thermal transport in nanoconfined water. The adsorptive interaction is only responsible for the layered distribution of thermal conductivity, while the repulsive interaction is responsible for the overall thermal conductivity; accordingly, the thermal conductivity is independent of the strength of water–solid interactions. The identified hierarchical thermal transport in nanoconfined water and its underlying mechanisms have a great significance for the understanding of nanoscale thermal transport and even the mass and energy transport of nanoconfined fluids.