A microelectromechanical system (MEMS) sensor was fabricated for testing low concentration gas sensing of sulphur dioxide (SO2) with sensing layers of single layer tin oxide (SnO2) and double layered heterojunction structure of nickel oxide and tin oxide (NiO/SnO2). NiO and SnO2 structures were deposited with RF sputtering and the elemental composition were identified with structural properties such as X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray (EDX) analysis. Sensing results proved that NiO/SnO2 double layered sensor had better sensing characteristics than single layered SnO2 sensor due to the formation of p-n junctions. At 400 ppb of SO2 gas concentration, NiO/SnO2 sensor has maximum sensing response of 20% is recorded and at 2000 ppb, 30% sensing response were recorded. The optimal temperature of the sensor is 250°C (~63 mW). Selectivity of the sensor is tested with 5 different gases and the sensor has high and better response with SO2 gas.
The micro-electro-mechanical systems (MEMS) method was used to fabricate a gas sensing element. The sensing layer uses radio-frequency sputter and plasma-enhanced atomic layer deposition (PE-ALD) technology to deposit indium oxide (InOx) thin films on Tin oxide (SnO2) to form an n-n type double-layer structure. The results show that the response of SnO2-InOx and monolayer SnO2 is 153% and 55%, respectively, which is an improvement of 98% under exposure to 0.6 ppm NO2, and the sensor can obtain the best sensing at 200℃ (~14 mW). In response, the lowest NO2 concentration was 0.2 ppm, and the selectivity test was carried out with four other gases, such as SO2, H2, CO, and NH3, and the test results showed the specificity for NO2.
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