Constructing efficient and cost-effective photocatalysts are highly desirable for photocatalytic hydrogen evolution. Herein, we prepare a unique 2D-2D architecture photocatalyst composed of CoP and ZnIn 2 S 4 (ZIS) nanosheets through electrostatic self-assembly method. The constructed 2D-2D CoP/ZIS exhibit a remarkably enhanced photocatalytic performance with hydrogen production rate of 8.775 mmol g −1 h −1 , and this value is much higher than ZIS and most of other ZISbased nanohybrids. Additionally, the nanohybrids possess excellent stability with 96.3% of initial activity remaining after 24 hours of testing. These satisfactory results are attributed to the large/intimate contact interface and the photo/electro-chemical properties of ZIS and CoP, which improves light absorption, facilitates photoelectron transport and suppresses charge recombination. This work not only demonstrates ZIS nanosheet can serve as a versatile and effective platform supporting non-noble metal nanosheets to boost their photocatalytic performance, but also offers a general and simple electrostatic self-assembly method to design 2D-2D-based heterostructures for hydrogen conversion from water splitting.

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