Soil-atmosphere exchange is important for the environmental fate and atmospheric transport of many semi-volatile organic compounds (SVOCs). This study focuses on modeling the vapor phase exchange of semi-volatile hydrophobic organic pollutants between soil and the atmosphere using the multicomponent reactive transport code MIN3P. MIN3P is typically applied to simulate aqueous and vapor phase transport and reaction processes in the subsurface. We extended the code to also include an atmospheric boundary layer where eddy diffusion takes place. The relevant processes and parameters affecting soil-atmosphere exchange were investigated in several 1-D model scenarios and at various time scales (from years to centuries). Phenanthrene was chosen as a model compound, but results apply for other hydrophobic organic compounds as well. Gaseous phenanthrene was assumed to be constantly supplied to the system during a pollution period and a subsequent regulation period (with a 50% decline in the emission rate). Our results indicate that long-term soil-atmosphere exchange of phenanthrene is controlled by the soil compartment - re-volatilization thus depends on soil properties. A sensitivity analysis showed that accumulation and transport in soils in the short term is dominated by diffusion, whereas in the long term groundwater recharge and biodegradation become relevant. As expected, sorption causes retardation and slows down transport and biodegradation. If atmospheric concentration is reduced (e.g. after environmental regulations), re-volatilization from soil to the atmosphere occurs only for a relatively short time period. Therefore, the model results demonstrate that soils generally are sinks for atmospheric pollutants. The atmospheric boundary layer is only relevant for time scales of less than one month. The extended MIN3P code can also be applied to simulate fluctuating concentrations in the atmosphere, for instance due to temperature changes in the topsoil.

No abstract

Understanding water flow through variably saturated waste‐rock dumps is important for determining the extent of sulfide‐mineral oxidation, contaminant loadings, and impacts of waste‐rock effluent on groundwater and surface‐water quality. To better understand water flow within full‐scale waste‐rock dumps in the continental subarctic region of Northern Canada, a field experiment was undertaken at the Main and Intermediate Dumps at the Faro Mine Complex, Yukon Territory. Here we present results from an investigation of the hydrological behavior and quantification of the factors controlling water flow through unsaturated waste‐rock dumps and the impacts on long‐term drainage water quality. The results suggest that flow through the fine matrix materials was the dominant flow mechanism, with possible preferential flow through macropores and ponding/runoff during intense infiltration events (i.e., snowmelt and intense rainfall). Cross δ18O‐δ2H plots of pore water collected from near‐surface waste‐rock samples suggested that evaporation at the surface of the dumps occurred during precipitation‐free periods in the summer. Depth profiles of δ18O and δ2H of pore water extracted from core samples provided indications of internal evaporation within the waste‐rock dumps and pore‐water displacement mainly in response to summer rainfall events (rather than snowmelt). Mixing calculations using δ18O and δ2H show that 76–95% of pore water present in the waste‐rock matrix was derived from summer rainfall, leading to lower concentrations of dissolved constituents in the summer effluent, and vice versa in winter. The results will inform cover design and remediation options for the waste‐rock dumps at the Faro Mine Complex.

No abstract

No abstract