The realization of high-quality (Q) resonators regardless of the underpinning material platforms has been a ceaseless pursuit, because the high-Q resonators provide an extreme environment for confining light to enable observations of many nonlinear optical phenomenon with high efficiencies. Here, photonic microresonators with a mean Q factor of 6.75 × 106 were demonstrated on a 4H-silicon-carbide-on-insulator (4H-SiCOI) platform, as determined by a statistical analysis of tens of resonances. Using these devices, broadband frequency conversions, including second-, third-, and fourth-harmonic generations have been observed. Cascaded Raman lasing has also been demonstrated in our SiC microresonator for the first time, to the best of our knowledge. Meanwhile, by engineering the dispersion properties of the SiC microresonator, we have achieved broadband Kerr frequency combs covering from 1300 to 1700 nm. Our demonstration represents a significant milestone in the development of SiC photonic integrated devices.
All-solid-state lithium-metal batteries
(ASSLMBs) with sulfide
electrolytes have attracted attention owing to their superior safety
and high energy density. However, interfacial instability of sulfide
electrolytes against Li metal still hinders their applications. Herein,
F-doping is adopted to optimize the structure of Li10SnP2S12. It is demonstrated that the Li9.95SnP2S11.95F0.05 (LSPSF) electrolyte
exhibits a high ionic conductivity of 6.4 mS cm–1 because of F-doping, which can reduce the impurity Li2SnS3 and generate Li+ vacancies. In addition,
the Li6PS5I (LPSI) glass–ceramic interlayer
is employed to enhance the interfacial stability between the sulfide
electrolyte and Li metal by restraining the reduction of Sn4+ cations, as indicated by X-ray photoelectron spectroscopy (XPS).
As a result, the assembled ASSLMBs with the LPSI interlayer deliver
high initial discharge capacity and remarkable cycling stability.
This work provides a new design route for manufacturing high-performance
ASSLMBs.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.