Ocean ventilation is the integrated effect of various processes that exchange surface properties with the ocean interior and is essential for oxygen supply, storage of anthropogenic carbon and the heat budget of the ocean, for instance. Current observational methods utilise transient tracers, e.g. tritium, SF6, CFCs and 14C. However, their dating ranges are not ideal to resolve the centennial-dynamics of the deep ocean, a gap filled by the noble gas isotope 39Ar with a half-life of 269 years. Its broad application has been hindered by its very low abundance, requiring 1000 L of water for dating. Here we show successful 39Ar dating with 5 L of water based on the atom-optical technique Atom Trap Trace Analysis. Our data reveal previously not quantifiable ventilation patterns in the Tropical Atlantic, where we find that advection is more important for the ventilation of the intermediate depth range than previously assumed. Now, the demonstrated analytical capabilities allow for a global collection of 39Ar data, which will have significant impact on our ability to quantify ocean ventilation.

Radiometric dating with 39 Ar covers a unique timespan and offers key advances in interpreting environmental archives of the last millennium. Although this tracer has been acknowledged for decades, studies so far have been limited by the low abundance and radioactivity, thus requiring huge sample sizes. Atom Trap Trace Analysis, an application of techniques from quantum physics such as laser cooling and trapping, allows to reduce the sample volume by several orders of magnitude, compared to conventional techniques. Here we show that the adaptation of this method to 39 Ar is now available for glaciological applications, by demonstrating the first Argon Trap Trace Analysis (ArTTA) dating of alpine glacier ice samples. Ice blocks as small as a few kilograms are sufficient and have been obtained at two artificial glacier caves. Importantly, both sites offer direct access to the stratigraphy at the glacier base and validation against existing age constraints. The ice blocks obtained at Chli Titlis glacier in 3030 m asl (Swiss Alps) have been dated by state-of-the-art microradiocarbon analysis in a previous study. The unique finding of a bark fragment and a larch needle within the ice of Schaufelferner glacier in 2870 m asl (Stubai Alps, Austria) allows for conventional radiocarbon dating. At both sites, results of 39 Ar dating match the existing age information based on radiocarbon dating and visual stratigraphy. With our results, we establish Argon Trap Trace Analysis as the key to decipher so far untapped glacier archives of the last millennium.

For an efficient performance of Atom Trap Trace Analysis, it is important to collimate the particles emitted from an effusive source. Their high velocity limits the interaction time with the cooling laser. Therefore forces beyond the limits of the scattering force are desirable. The bichromatic force is a promising candidate for this purpose which is demonstrated here for the first time on metastable argon-40. The precollimated atoms are deflected in one dimension and the acquired Doppler shift is detected by absorption spectroscopy. With the experimentally accessible parameters, it was possible to measure a force three times stronger than the scattering force. Systematic studies on its dependence on Rabi frequency, phase difference and detuning to atomic resonance are compared to the solution of the optical Bloch equations. We anticipate predictions for a possible application in Atom Trap Trace Analysis of argon-39 and other noble gas experiments, where a high flux of metastable atoms is needed.