Vertical stacking of monolayers via van der Waals (vdW) interaction opens promising routes toward engineering physical properties of two-dimensional (2D) materials and designing atomically thin devices. However, due to the lack of mechanistic understanding, challenges remain in the controlled fabrication of these structures via scalable methods such as chemical vapor deposition (CVD) onto substrates. In this paper, we develop a general multiscale model to describe the size evolution of 2D layers and predict the necessary growth conditions for vertical (initial + subsequent layers) versus in-plane lateral (monolayer) growth. An analytic thermodynamic criterion is established for subsequent layer growth that depends on the sizes of both layers, the vdW interaction energies, and the edge energy of 2D layers. Considering the time-dependent growth process, we find that temperature and adatom flux from vapor are the primary criteria affecting the self-assembled growth. The proposed model clearly demonstrates the distinct roles of thermodynamic and kinetic mechanisms governing the final structure. Our model agrees with experimental observations of various monolayer and bilayer transition metal dichalcogenides grown by CVD and provides a predictive framework to guide the fabrication of vertically stacked 2D materials.

A perfect ultra-narrow band infrared metamaterial absorber based on the all-metal-grating structure is proposed. The absorber presents a perfect absorption efficiency of over 98% with an ultra-narrow bandwidth of 0.66 nm at normal incidence. This high efficient absorption is contributed to the surface plasmon resonance. Moreover, the surface plasmon resonance-induced strong surface electric field enhancement is favorable for application in biosensing system. When operated as a plasmonic refractive index sensor, the ultra-narrow band absorber has a wavelength sensitivity 2400 nm/RIU and an ultra-high figure of merit 3640, which are much better than those of most reported similar plasmonic sensors. Besides, we also comprehensively investigate the influences of structural parameters on the sensing properties. Due to the simplicity of its geometry structure and its easiness to be fabricated, the proposed high figure of merit and sensitivity sensor indicates a competitive candidate for applications in sensing or detecting fields.

A surface plasmon polaritons (SPPs) refractive index sensor which consists of two metal-insulator-metal (MIM) waveguides coupled to each other by a ring resonator is proposed. The transmission properties are numerically simulated by finite element method. The sensing characteristics of such structure are systematically analyzed by investigating the transmission spectrum. The results indicate that there exist three resonance peaks in the transmission spectrum, and all of which have a linear relationship with the refractive index of the material under sensing. Through the optimization of structural parameters, we achieve a theoretical value of the refractive index sensitivity as high as 3460nmRIU(-1). Furthermore, this structure can also be used as a temperature sensor with temperature sensitivity of 1.36nm/°C. This work paves the way toward sensitive nanometer scale refractive index sensor and temperature sensor for design and application.

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We propose and numerically investigate a perfect ultra-narrowband absorber with an absorption bandwidth of only 1.82 nm and an absorption efficiency exceeding 95% in the visible region. We demonstrate that the perfect ultra-narrowband absorption is ascribed to the coupling effect induced by localized surface plasmon resonance. The influence of structural dimensions on the optical performance is also investigated, and the optimal structure is obtained with the extremely low reflectivity (0.001) of the resonance dip. The perfect absorber can be operated as a refractive index sensor with a sensitivity of around 425 nm/RIU and the figure of merit (FOM) reaching 233.5, which greatly improves the accuracy of the plasmonic sensors in visible region. Moreover, the corresponding figure of merit (FOM*) for this sensor is also calculated to describe the performance of the intensity change detection at a fixed frequency, which can be up to 1.4 × 105. Due to the high sensing performance, the metamaterial structure has great potential in the biological binding, integrated photodetectors, chemical applications and so on.