The excessive expansion of urbanized areas has resulted in haphazard land utilization, immoderate consumption of superior agricultural land and water resources, significant fragmentation of agricultural landscape, and gradual deterioration of the agro-ecological environment. Combined, these factors cause poor land use efficiency. Under these circumstances, comprehensively assessing land use efficiency for urban agriculture is a key issue in land use research. Currently, evaluation methods for agricultural land use efficiency narrowly concentrate on aspects of economic input and output. However, urban agro-ecosystems can provide diverse economic, social, and ecological services and functions. In particular, the social and ecological services and functions originating from agricultural land, which have a higher value than economic services, play a significant role in ensuring regional social, ecological, and environmental security. However, recent research has rarely taken these benefits into consideration. Therefore, land use value has been greatly underestimated, which has resulted in mishandled and poor land use policies. In this study, we apply Landsat imagery and social and economic statistical data for the Xi'an metropolitan zone (XMZ) to investigate agricultural multi-functionality. We develop an evaluation framework for urban agricultural land use efficiency and identify agro-ecosystem services and functions as important outputs from agricultural land. The land use efficiency of urban agriculture is then evaluated using ecosystem services models, providing a mechanism for assessing spatial-temporal changes in land use efficiency in the XMZ from 1999 to 2015. Four important conclusions are reached from this analysis. First, the rapid urbanization and agricultural transformation from traditional cereal cultivation to modern urban agriculture has resulted in steadily increasing costs, outputs, and land use efficiency of urban agriculture. The total output value increased 41% and land use efficiency per hectare increased by 33.13% on average. Second, the spatial patterns of comprehensive output and land use efficiency were dominated by economic outputs from agricultural land. Areas near cities, which are dominated by orchard and arable land, provide Keywords: urban agriculture; land use efficiency; agro-ecosystem services; agricultural multi-functionality; Xi'an metropolitan zone (XMZ)