Polarization-sensitive photodetectors are highly desirable for high-performance optical signal capture and stray light shielding in order to enhance the capability for detection and identification of targets in dark, haze, and other complex environments. Usually, filters and polarizers are utilized for conventional devices to achieve polarization-sensitive detection. Herein, to simplify the optical system, a two-dimensional self-powered polarization-sensitive photodetector is fabricated based on a stacked GeSe/MoS2 van der Waals (vdW) heterojunction which facilitates efficient separation and transportation of the photogenerated carriers because of type-II band alignment. Accordingly, a high-performance self-powered photodetector is achieved with merits of a very large on–off ratio photocurrent at zero bias of currently 104 and a high responsivity (R λ) of 105 mA/W with an external quantum efficiency of 24.2%. Furthermore, a broad spectral photoresponse is extended from 380 to 1064 nm owing to the high absorption coefficient in a wide spectral region. One of the key benefits from these highly anisotropic orthorhombic structures of layered GeSe is self-powered polarization-sensitive detection with a peak/valley ratio of up to 2.95. This is realized irradiating with a 532 nm wavelength laser with which a maximum photoresponsivity of up to 590 mA/W is reached when the input polarization is parallel to the armchair direction. This work provides a facile route to fabricate self-powered polarization-sensitive photodetectors from GeSe/MoS2 vdW heterojunctions for integrated optoelectronic devices.

The design, fabrication, characterization, and modeling of basic building blocks of plasmonic circuitry based on dielectric-loaded surface polariton waveguides, such as bends, splitters, and Mach-Zehnder interferometers are presented. The plasmonic components are realized by depositing subwavelength dielectric ridges on a smooth gold film using mass-production-compatible UV-photolithography. The near-field characterization at telecommunication wavelengths shows the strong mode confinement and low radiation and bend losses. The performance of the devices is found in good agreement with results obtained by full vectorial three-dimensional finite element simulations.

N-nitrosodimethylamine (NDMA)formation in chloraminated Iowa River water (IRW) is primarily attributed to reactions with natural organic matter (NOM) generally classified as humic substances. Experiments were conducted to determine the contribution of various NOM humic fractions to the NDMA formation potential (NDMA FP) in this drinking water source. NOM was concentrated by reverse osmosis (RO) and humic fractions were obtained by a series of resin elution procedures. Mass balances showed that nearly 90% of the NDMA formation potential could be recovered in the NOM concentrate and in water reconstituted using additions of the various humic fractions. Generally, the hydrophilic fractions tended to form more NDMA than hydrophobic fractions, and basic fractions tend to form more NDMA than acid fractions when normalized to a carbon basis. Overall, the hydrophobic acid fraction was the dominant source of NDMA when both formation efficiency and water composition were considered. The amount of NDMA formed in a sample was found to correlate linearly with an oxidation-induced decrease in specific UV absorbance (SUVA) value at 272 nm. This is consistent with a mechanism in which precursors are formed as the direct consequence of the oxidation of NOM. The NDMA FP estimated using the slope of this relationship and the initial SUVA value compared closely to the value obtained by measuring the NDMA formed in solutions dosed with excess concentrations of monochloramine that presumably exhaust all potential precursor sources. However, the NOMA FP could not be correlated to the SUVA value of the individual humic fractions indicating that the relationship of the NDMA FP to SUVA value is probably a water-specific parameter dependent on the exact composition of humic fractions. It is hypothesized that either specific NDMA precursors are distributed among the various humic fractions or that the humic material itself represents a "generic" nonspecific precursor source that requires some degree of oxidation to eventually produce NDMA. The nonmonotonic behavior of NOM fluorescence spectra during chloramination and lack of correlation between NOM fluorescence characteristics and NDMA formation limited the usage of fluorescence spectra into probing NDMA formation.

Biomass waste has emerged as a novel sustainable and renewable material for fabricating functional materials because of the lightweight and easy manufacturing. Herein, we synthesize a porous Fe 3 O 4 /carbon fiber (Fe 3 O 4 /CF) composites derived from bagasse waste by in-situ growth and a graphitization process. The Fe 3 O 4 nanocrystals uniformly embedded in porous CF significantly construct the multiple interfaces and hierarchical microstructure of Fe 3 O 4 /CF composites. Fe 3 O 4 /CF composites exhibit a maximum reflection loss value of −48.2 dB at 15.6 GHz with a thin thickness of only 1.9 mm. Meanwhile, a broad effective absorption bandwidth of 5.1 GHz covering the frequency range of 12.9−18.0 GHz is achieved. The rough surface, porous structure, and proper component contribute to the improved impedance matching. Meanwhile, the Debye relaxation and interfacial polarization dominantly promote the attenuation ability of the microwave. The enhancement of attenuation ability and impedance matching together account for the superior microwave absorption performance.