Quantum-confined CsPbBr 3 nanoplatelets (NPLs) with narrow full width at half-maximum (FWHM), large exciton binding energies, and precisely tunable thickness have become one of the promising materials for lighting and display. Still, the synthesis of CsPbBr 3 NPLs with high photoluminescence (PL) intensity and excellent stability is challenging, hindering their large-scale application in lighting devices. Herein, we present a facile post-treatment strategy to enhance the PL performance of CsPbBr 3 NPLs by surface passivation with a ZnBr 2 solution. The ZnBr 2 -treated CsPbBr 3 NPLs exhibit 90% photoluminescence quantum yield (PLQY) in the dispersion at 461 nm and 50% PLQY in thin films. Benefiting from surface defect passivation and ion migration suppression, ZnBr 2treated CsPbBr 3 NPLs exhibit outstanding stability over pristine CsPbBr 3 NPLs during long-term storage and exposure to a polar solution, light, and heating treatment. Specifically, the PL intensity of ZnBr 2 -treated CsPbBr 3 NPLs dispersion shows a little decrease after storage at ambient conditions for 50 days or after mixing with ethanol for 160 h. Under challenging conditions including exposure to ultraviolet light for 300 h or heating at 70 °C for 30 min, their PLQY decreases only slightly.
Ultra-thin asphalt overlay has become the mainstream measure of road preventive maintenance due to its good economic benefits and road performance. However, hot mix asphalt concrete technology is widely used at present, which is not the most ideal way to promote energy saving and emission reduction in the field of road maintenance. At the same time, the ultra-thin friction course based on cold mix technology, such as slurry seal layer, micro-surface, and other technologies, are still far behind the hot mix friction course in terms of crack resistance. In this research, by establishing an integrated design of materials and structures, a cold paving technology called “high-toughness cold-mixed ultra-thin pavement (HCUP)” is proposed. The high-viscosity emulsified bitumen prepared by using high-viscosity and high-elasticity modified bitumen is used as the binder and sticky layer of HCUP. The thickness of HCUP is 0.8–2.0 cm, the typical thickness is 1.2 cm, and the nominal maximum size of the coarse aggregate is 8 mm. Indoor tests show that HCUP-8 has water stability, anti-skid performance, high temperature performance, peeling resistance, and crack resistance that are not weaker than traditional hot-mixed ultra-thin wear layers such as AC-10, Novachip, and GT-8. At the same time, the test road paving further proved that HCUP-8 has excellent road performance with a view to providing new ideas for low-carbon and environmentally friendly road materials.
Magic-size clusters (MSCs) are molecular-like materials with unique properties at the border between molecules and solids, providing important insights into the nanocrystal formation process. However, the synthesis of multicomponent alloy...
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