A facile one-step route was developed to synthesize crystalline CuGeO₃ nanowire/graphene composites (CGCs). Crystalline CuGeO₃ nanowires were tightly covered and anchored by graphene sheets, forming a layered structure. Subsequently, CGCs were exploited as electrode materials for lithium ion batteries (LIBs). The reversible formation of Li₂O buffer layer and elastic graphene sheets accommodated the volume change during the charge and discharge processes. CGC containing 37 wt% graphene exhibited a superior electrochemical performance, that is, a remarkable reversible capacity (1265 mA h g(-1) for the first cycle), an outstanding cyclic performance (853 mA h g(-1) after 50 cycles under a current density of 200 mA g(-1)), a high coulombic efficiency, and an excellent rate capability. Clearly, CGCs may stand out as a promising anode material for LIBs.
Gas chromatography–olfactometry coupled with sensory
analysis and partial least-squares regression (PLSR) analysis led
to the identification of the odorants responsible for the different
flavors of four yeast extracts. Sensory analysis showed that LA00L
had an intense sulfurous attribute, and LA00 was characterized by
fatty and green notes, FA31 exhibited the floral odor, while KA02
had strong phenolic, animal, fermented, roasted, and caramellic notes.
A total of 37 key aroma compounds with odor activity values greater
than 1 were determined. 2,4-Di-tert-butylphenol and
methional were the most potent aroma compounds. In addition, the key
aroma compounds in LA00L were nonanal, dimethyl disulfide, and γ-decalactone.
Octanal, dimethyl disulfide, and benzeneacetaldehyde were the key
aroma compounds in LA00. In FA31, styrene, benzeneacetaldehyde, and
acetophenone were the key aroma compounds, while indole, 2-methoxyphenol,
benzeneacetaldehyde, and p-cresol contributed significantly
to the aroma of KA02. PLSR showed that p-cresol and
indole were significantly responsible for the phenolic and animal
notes inducing the off-flavor (yeasty odor) of yeasty extracts. More
significantly, indole was first reported to have an important effect
on yeasty odor.
Size-tunable crystalline core-crystalline shell Zn2GeO4 nanorods were synthesized via a facile hydrothermal reaction. High purity Zn2GeO4 nanorods were obtained at pH = 7. The length of Zn2GeO4 nanorods (L = 50-100 nm) can be controlled through a one-step process, while micro-sized nanorods with an aspect ratio of the length to the diameter of 10 were yielded in a two-step process. The single crystalline nature of Zn2GeO4 nanorods with a core-shell structure was verified by high resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED) measurements. The Raman study revealed that there is no oxygen defect in Zn2GeO4 nanocrystals, suggesting that photoluminescence emission of Zn2GeO4 can be attributed to the presence of the interstitial Zn defect in Zn2GeO4 nanocrystals. As the diameter of nanorods decreased, the excitation and emission peaks appeared to be redshifted due to the quantum size effect.
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