Solar cells based on organometal halide perovskites have recently become very promising among other materials because of their cost-effective character and improvements in efficiency. Such performance is primarily associated with effective light absorption and large diffusion length of charge carriers. Our paper is devoted to the explanation of large diffusion lengths in these systems.The transport mean free path of charged carriers in a perovskite/TiO 2 heterojunction that is an important constituent of the solar cells have been analyzed. Large transport length is explained by the planar diffusion of indirect excitons. Diffusion length of the coupled system increases by several orders compared to single carrier length due to the correlated character of the effective field acting on the exciton.
The complete set of optical parameters of micron-sized polycrystalline CH 3 NH 3 PbI 3−x Cl x films deposited by the vacuum co-evaporation of lead iodide and methylammonium chloride is determined by analysis of oscillating optical transmittance and reflectance spectra in the wavelength range 400-1000 nm. It is shown that for a medium and weak absorption region the envelope method is valid for the extraction of refractive index, extinction and absorption coefficient when is using only transmittance spectra. As well thickness of the film is determined from transmittance and reflectance spectra with interference-effect. The absorption coefficient for the strong absorption region and optical band gap (direct transition at E opt =1.62 eV) are calculated based on transmittance and reflectance spectra by using conventional approximated formulas.
We have analyzed analytically the Faraday rotation of an electromagnetic wave for magnetoactive thin metallic film with a nanostructured surface profile. Periodical as well as random surface profiles were considered. The plasmon contribution to the Faraday angle was studied. For periodical grating case, we have shown that the maximum of rotation angle is achieved when surface plasmon wave number coincides with one of the wave numbers of the inverse lattice. Enhancement of the Faraday angle at plasmonic band edges is predicted. In the case of random surface profile, it is shown that the diffusion of surface magnetoplasmons gives a dominant contribution to Faraday rotation. Comparison with the experiments is carried out.
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