No abstract

Recent observation of diminishing superfluid phase stiffness upon increasing carrier density in cuprate high-temperature superconductors is unexpected from the quantum density-phase conjugation of superfluidity. Here, through analytic estimation and verified via variational Monte Carlo calculation of an emergent Bose liquid, we point out that Mottness of the underlying carriers can cause a stronger phase fluctuation of the superfluid with increasing carrier density. This effect turns the expected density-increased phase stiffness into a dome shape, in good agreement with the recent observation. Specifically, the effective mass divergence due to "jamming" of the low-energy bosons reproduces the observed nonlinear relation between phase stiffness and transition temperature. Our results suggest a new paradigm, in which unconventional superconductivity in some strongly correlated materials is described by physics of bosonic superfluidity, as opposed to pairing-strength limited Cooper pairing.

Recently discovered superconductivity in hole-doped nickelate Nd 0.8 Sr 0.2 NiO 2 caught intensive attention in the field. An immediate question is how to improve its superconducting properties. Guided by the key characteristics of electronic structures of the cuprates and the nickelates, we propose that nickel chalcogenides with a similar lattice structure should be a promising family of materials. Using NdNiS 2 as an example, we find this particular crystal structure a stable one, through first-principle structural optimization and phonon calculation. We justify our proposal by comparing with CaCuO 2 and NdNiO 2 the strength of the charge-transfer characteristics and the trend in their low-energy many-body effective Hamiltonians of doped hole carriers. These analysis indicates that nickel chalcogenides host low-energy physics closer to that of the cuprates, with stronger magnetic interaction than the nickelates, and thus deserve further experimental exploration. Our proposal also opens up the possibility of a wide range of parameter tuning through ligand substitution among chalcogenides, to further improve superconducting properties.

Recent observations of diminishing superfluid phase stiffness in overdoped cuprate hightemperature superconductors challenges the conventional picture of superconductivity. Here, through analytic estimation and verified via variational Monte Carlo calculation of an emergent Bose liquid, we point out that Mottness of the underlying doped holes dictates a strong phase fluctuation of the superfluid at moderate carrier density. This effect turns the expected doping-increased phase stiffness into a dome shape, in good agreement with the recent observation. Specifically, the effective mass divergence due to "jamming" of the low-energy bosons reproduces the observed nonlinear relation between phase stiffness and transition temperature. Our results suggest a new paradigm, in which the high-temperature superconductivity in the cuprates is dominated by physics of Bose-Einstein condensation, as opposed to pairing-strength limited Cooper pairing.