Comprehensive SummaryA transition‐metal free three‐component coupling reaction of azaindoles, C60, and bromoalkanes/triphenylamines has been developed to provide an efficient access to diverse azaindole functionalized 1,4‐C60 adducts. This protocol exhibits low cost, operational simplicity, wide substrate scope, and mild and convenient conditions.This article is protected by copyright. All rights reserved.

A transition-metal free three-component coupling reaction of azaindoles, C60, and bromoalkanes/triphenylamines has been developed to provide an efficient access to diverse azaindole functionalized 1,4-C60 adducts. This protocol exhibits low cost, operational-simplicity, wide substrate scope, and mild and convenient conditions.

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