Three dimensional (3D) Dirac semimetal is a novel state of quantum matter, characterized by the gapless bulk four-fold degeneracy near Fermi energy. Soon after its discovery, the classification of stable 3D Dirac semimetals with inversion and rotational symmetry have been studied. However, only ten out of thirty-two point groups have both inversion and rotational symmetry, and we need a more complete classification of stable 3D Dirac semimetals. Here we classify stable 3D Dirac semimetals with reflection symmetry and rotational symmetry in the presence of time reversal symmetry, which belong to seventeen different point groups. These systems include the systems preserving inversion symmetry except C3i. They have two classes of reflection symmetry, with the mirror plane parallel to rotation axis and the mirror plane perpendicular to rotation axis. In both cases two types of Dirac semimetals are determined by four different reflection symmetries. The first type of Dirac semimetals will appear through accidental band crossing (ABC). The second type of Dirac semimetals have a Dirac point at a time reversal invariant momentum (TBC). We show that in both mirror parallel and perpendicular cases, C2,3 symmetry can only protect stable Dirac points via TBC, while C4,6 symmetry can have stable Dirac points as ABC or TBC. We further discuss that Weyl line nodes and Dirac semimetal can exist in Brillouin zone at the same time using C4v symmetry as an example. Finally we classify Dirac line nodes and Weyl line nodes to show in which types of mirror plane they can exist.

a b s t r a c tThe quantal release of oxidizable molecules can be successfully monitored by means of polarized carbon fiber microelectrodes (CFEs) positioned in close proximity to the cell membrane. To partially overcome certain CFE limitations, mainly related to their low spatial resolution and lack of optical transparency, we developed a planar boron-doped nanocrystalline diamond (NCD) prototype, grown on a transparent sapphire wafer. Responsiveness to applied catecholamines as well as the electrochemical and optical properties of the NCD-based device were first characterized by cyclic voltammetry and optical transmittance measurements. By stimulating chromaffin cells positioned on the device with external KCl, well-resolved quantal exocytotic events could be detected either from one NCD microelectrode, or simultaneously from an array of four microelectrodes, indicating that the chip is able to monitor secretory events (amperometric spikes) from a number of isolated chromaffin cells. Spikes detected by the planar NCD device had comparable amplitudes, kinetics and vesicle diameter distributions as those measured by conventional CFEs from the same chromaffin cell.

Extra-large and intersecting pores Thermally stable zeolites with large pores, such as zeolite Y with 12-membered rings, are used for converting large molecules from petroleum into smaller, more useful hydrocarbons. Lin et al . report the synthesis of ZEO-1, a thermally stable zeolite with extra-large, 16-membered rings. The use of tricyclohexylmethylphosphonium as an organic structure–directing agent created a zeolite with a fully interconnected multidimensional framework and a very high specific surface area. —PDS