An increasing amount of waste seashells in China has caused serious environmental pollution and resource waste. This paper aims to solve these problems by using waste seashells as modified materials to prepare high-performance modified asphalt. In this study, seashell powder (SP) and stratum corneum-exfoliated seashell powder (SCESP) were adopted to prepare 10%, 20% and 30% of seashell powder-modified asphalt (SPMA) and stratum corneum-exfoliated seashell powder-modified asphalt (SCESPMA) by the high-speed shear apparatus, respectively. The appearance and composition of two kinds of SPs were observed and determined by the scanning electron microscope (SEM). The types of functional groups, temperature frequency characteristics, low temperature performance and adhesion of SPMA were tested by the Fourier-transform infrared (FTIR) spectrometer, dynamic shear rheometer (DSR), bending beam rheometer (BBR) and contact angle meter. The results show that the SP and SCESP are rough and porous, and their main component is CaCO3, which is physically miscible to asphalt. When the loading frequency ranges from 0.1 Hz to 10 Hz, the complex shear modulus (G*) and phase angle (δ) of SPMA and SCESPMA increase and decrease, respectively. At the same load frequency, SCESPMA has a larger G* and a smaller δ than SPMA. At the same temperature, SCESPMA has a larger rutting factor (G*/sin δ) and better high-temperature deformation resistance than SPMA. SP and SCESP reduce the low-temperature cracking resistance of asphalt, of which SCESP has a more adverse effect on the low-temperature performance of asphalt than SP. When SP and SCESP are mixed with asphalt, the cohesion work (Waa), adhesion work (Was) and comprehensive evaluation parameters of water stability (ER1, ER2 and ER3) of asphalt are improved. It is shown that both SP and SCESP have good water damage resistance, of which SCESP has better water damage resistance than SP. These research results have important reference value for the application of waste biological materials in asphalt pavement.

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With the continuous development of road construction and maintenance, SBS(Styrene-butadiene-styrene)-modified asphalt is widely used. However, there is no mature method for restoring aged SBS-modified asphalt. This study proposes the use of SBR(polymerized styrene butadiene rubber) and bio-oil for the restoration of aged SBS. In this study, five kinds of recycled asphalt were prepared by adding 5% bio-oil, 10% bio-oil, 6% SBR, 6% SBR + 5% bio-oil, and 6% SBR + 10% bio-oil to long-term aged SBS-modified asphalt. Softening point, penetration, and rotational viscosity experiments were tested to evaluate the conventional properties. Rheological tests revealed the performance of asphalt. Fourier transform infrared spectroscopy (FTIR), and atomic force microscope (AFM) tests were tested to demonstrate the microscopic characteristics of asphalt. Conventional tests investigated that aged asphalt viscosity will increase. Bio-oil could well recycle the asphalt viscosity. SBR could also soften aged asphalt, but its modification effect is limited compared with bio-oil. Rheological tests presented that the SBR and bio-oil have little impact on the temperature sensitivity of SBS-modified asphalt. SBR and bio-oil could decrease the asphalt stiffness. However, SBR and bio-oil could ameliorate the anti-cracking behavior of aged asphalt. The microscopic tests exhibited that SBR and bio-oil could decrease the asphaltene and colloid. Meanwhile, bio-oil could supplement alcohols and ethers at wave number 1000 cm−1–1270 cm−1. Alcohols and ethers are hard to oxidize, something which has a beneficial role in the anti-aged of recycled asphalt.

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