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Rechargeable lithium-ion and sodium-ion batteries (SIB) have dominated the energy storage fields such as electric vehicles and portable electronics due to their high energy density, long cycle life, and environmental friendliness. However, the critical bottleneck hindering the further improvement of their electrochemical performance is the unsatisfactory cathode materials, typically exhibiting inherent drawbacks such as low reversible capacity, initial capacity loss, fast capacity decay, and poor rate performance. These issues are mainly attributed to changes in the internal structure of cathode materials, such as irreversible transformation of particle morphology, evolution of crystal structure, and undesired physicochemical interfacial reactions during the electrochemical process. To address above obstacles, abundant research efforts have been devoted to stabilizing the structural evolution of cathode materials and enhancing their electrochemical performance. Herein, we reviewed the research progress on the cathode materials for lithium-ion and SIBs. The typical cathodes and their structural characteristics, electrochemical behaviors, reaction mechanisms, and strategies for electrochemical performance optimization were summarized. This review aims to promote the understanding of the structure-performance relationship in the cathode materials and provide some guidance for the design of advanced cathode materials for lithium-ion and SIBs from the perspective of crystal structure.

Oxygen redox (OR) chemistry has been an attractive topic in the field of high-energy lithium-ion batteries, as it enables extra storage of charge and boosts the capacity of highly potential...

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