Cavity-enhanced resonant photoacoustic spectroscopy with optical feedback cw diode lasers: A novel technique for ultratrace gas analysis and high-resolution spectroscopy J. Chem. Phys. 133, 044308 (2010) Electromechanical probing of ionic currents in energy storage materials Appl. Phys. Lett. 96, 222906 (2010) Broadening effects and ergodicity in deep level photothermal spectroscopy of defect states in semi-insulating GaAs: A combined temperature-, pulse-rate-, and time-domain study of defect state kinetics J. Appl. Phys. 105, 103712 (2009) Measurement of the redistribution of arsenic at nickel silicide/silicon interface by secondary ion mass spectrometry: artifact and optimized analysis conditions J. Appl. Phys. 104, 024313 (2008) Standoff photoacoustic spectroscopy Appl. Phys. Lett. 92, 234102 (2008) Additional information on Rev. Sci. Instrum.The application of different types of acoustic resonators such as pipes, cylinders, and spheres in photoacoustics is considered. This includes a discussion of the fundamental properties of these resonant cavities. Modulated and pulsed laser excitation of acoustic modes is discussed. The theoretical and practical aspects of high-Q and low-Q resonators and their integration into complete photoacoustic detection systems for trace gas monitoring and metrology are covered in detail. The characteristics of the available laser sources and the performance of the photoacoustic resonators, such as signal amplification, are discussed. Setup properties and noise features are considered in detail. This review is intended to give newcomers the information needed to design and construct state-of-the-art photoacoustic detectors for specific purposes such as trace gas analysis, spectroscopy, and metrology.

Abstract. In aerosol chamber experiments optical properties of resuspended mineral dust samples of defined size distributions were measured. Extinction coefficients (b ext ) and mass specific extinction cross sections (σ ext ) were determined for Saharan dust samples from different locations. The results for σ ext were not very sensitive to the type of dust and varied at λ=550 nm between 3.3±0.4 m 2 g −1 and 3.7±0.4 m 2 g −1 .The absorption coefficients (b abs ) and mass specific absorption cross sections (σ abs ) were determined with a novel multiwavelength photo-acoustic absorption spectrometer (PAS). The single scattering albedo was close to 1 (0.98 to 0.99) at 532 nm and 1064 nm, but significantly lower (0.63 to 0.76) at 266 nm. Additionally the chemical and mineralogical composition of the dust samples were analysed with special regard to the iron oxide phases hematite and goethite. At λ=266 nm the mineral dust sample without any detectable iron oxides showed a significantly higher SSA compared to the sample with a hematite content of 0.6 wt-%.

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Abstract. The AquaVIT-1 intercomparison of atmospheric water vapor measurement techniques was conducted at the aerosol and cloud simulation chamber AIDA (Aerosol Interaction and Dynamics in the Atmosphere) at the Karlsruhe Institute of Technology, Germany, in October 2007. The overall objective was to intercompare state-of-the-art and prototype atmospheric hygrometers with each other and with independent humidity standards under controlled conditions. This activity was conducted as a blind intercomparison with coordination by selected referees. The effort was motivated by persistent discrepancies found in atmospheric measurements involving multiple instruments operating on research aircraft and balloon platforms, particularly in the upper troposphere and lower stratosphere, where water vapor reaches Published by Copernicus Publications on behalf of the European Geosciences Union. D. W. Fahey et al.: The AquaVIT-1 water vapor intercomparisonits lowest atmospheric values (less than 10 ppm). With the AIDA chamber volume of 84 m 3 , multiple instruments analyzed air with a common water vapor mixing ratio, by extracting air into instrument flow systems, by locating instruments inside the chamber, or by sampling the chamber volume optically. The intercomparison was successfully conducted over 10 days during which pressure, temperature, and mixing ratio were systematically varied (50 to 500 hPa, 185 to 243 K, and 0.3 to 152 ppm). In the absence of an accepted reference instrument, the absolute accuracy of the instruments was not established. To evaluate the intercomparison, the reference value was taken to be the ensemble mean of a core subset of the measurements. For these core instruments, the agreement between 10 and 150 ppm of water vapor is considered good with variation about the reference value of about ±10 % (±1σ ). In the region of most interest between 1 and 10 ppm, the core subset agreement is fair with variation about the reference value of ±20 % (±1σ ). The upper limit of precision was also derived for each instrument from the reported data. The implication for atmospheric measurements is that the substantially larger differences observed during in-flight intercomparisons stem from other factors associated with the moving platforms or the non-laboratory environment. The success of AquaVIT-1 provides a template for future intercomparison efforts with water vapor or other species that are focused on improving the analytical quality of atmospheric measurements on moving platforms.

Abstract. For almost two decades, the airborne Fast In-situ Stratospheric Hygrometer (FISH) has stood for accurate and precise measurements of total water mixing ratios (WMR, gas phase + evaporated ice) in the upper troposphere and lower stratosphere (UT/LS). Here, we present a comprehensive review of the measurement technique (Lyman-α photofragment fluorescence), calibration procedure, accuracy and reliability of FISH. Crucial for FISH measurement quality is the regular calibration to a water vapor reference, namely the commercial frost-point hygrometer DP30. In the frame of this work this frost-point hygrometer is compared to German and British traceable metrological water standards and its accuracy is found to be 2–4 %. Overall, in the range from 4 to 1000 ppmv, the total accuracy of FISH was found to be 6–8 %, as stated in previous publications. For lower mixing ratios down to 1 ppmv, the uncertainty reaches a lower limit of 0.3 ppmv. For specific, non-atmospheric conditions, as set in experiments at the AIDA chamber – namely mixing ratios below 10 and above 100 ppmv in combination with high- and low-pressure conditions – the need to apply a modified FISH calibration evaluation has been identified. The new evaluation improves the agreement of FISH with other hygrometers to ± 10 % accuracy in the respective mixing ratio ranges. Furthermore, a quality check procedure for high total water measurements in cirrus clouds at high pressures (400–500 hPa) is introduced. The performance of FISH in the field is assessed by reviewing intercomparisons of FISH water vapor data with other in situ and remote sensing hygrometers over the last two decades. We find that the agreement of FISH with the other hygrometers has improved over that time span from overall up to ± 30 % or more to about ± 5–20 % @ < 10 ppmv and to ± 0–15 % @ > 10 ppmv. As presented here, the robust and continuous calibration and operation procedures of the FISH instrument over the last two decades establish the position of FISH as one of the core instruments for in situ observations of water vapor in the UT/LS.