Biogas slurry, also called liquid digestate, refers to the liquid part of the anaerobic digestate produced from the anaerobic digestion process, which is an environmental pollution source if it is discharged without proper treatment. To recover the nutrients in the biogas slurry, a membrane system was designed to concentrate in the work. The effects of pretreatment technology including gravity settling and ultrafiltration process were studied via analyzing the chemical oxygen demand (COD), ammonia nitrogen (NH 3 -N), total nitrogen (TN), and conductivity. Reverse osmosis was applied in the biogas slurry concentration. The performance of reverse osmosis membrane used in the concentration process was studied by analyzing the permeate and concentrate (retentate), the volume reduction factor, and the concentration factor. The suitable parameters were selected as 20.0-25.0°C for influent temperature, 0.8-1.0Mpa for operating pressure, and 6.0-8.0 for influent pH. Furthermore, the feasible concentration factor was evaluated as 4. The economic, environmental, and social benefits could be gained if (concentrated) biogas slurry was used as a substitute for chemical fertilizers. © 2019 Water Environment FederationPractitioner points • Reverse osmosis system was established for biogas slurry concentrating. • The operational factors were optimized on biogas slurry concentrating and separation. • The biogas slurry separation mechanism was discussed.

The liquid digestate has been regarded as a potential organic fertilizer for its benefit in nutrients recovery. However, the potential risk of hazardous substances remaining in the wastewater was still one of the main obstacles for the wastewater application in the circular agriculture. The pretreatment is important to remove pollutants with relatively satisfied results. Ferric coagulation was a feasible way to simultaneously remove various contaminants in the wastewater with few residuals of ferric ions under alkaline and neutral conditions. In special, it could reduce the residues of sulfide and arsenic compounds. We gained insights into the mechanism of ferric coagulation in removing sulfide and arsenic compounds. Redox reaction and precipitation were the reasons resulting in removing sulfide. The formation of precipitate by combining with iron(III) contributes to the removal of arsenic compounds. Toxicity tests using Scenedesmus obliquus and Chlorella pyrenoidosa showed an obvious reduction of toxicity for the liquid digestate after ferric coagulation. Besides, ferric coagulation could efficiently remove turbidity, reduce COD, and eliminate dissolved organic matters correlated with the fate of heavy metal and antibiotics. Therefore, this paper could give basic data and technique supports for the secure utilization and pollution control of liquid digestate. Practitioner points Most sulfide and arsenic compounds were removed by 0.01 M ferric coagulation. Mechanisms on removing hazardous substances by ferric coagulation were discussed based on analysis of X‐ray photoelectron spectroscopy and FTIR. The evaluation by two algae showed the toxicity of liquid digestate could be reduced obviously after ferric coagulation.

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