Liquid crystal elastomers (LCEs) are programmable deformable materials that can respond to physical fields such as light, heat, and electricity. Photothermal-driven LCE has the advantages of accuracy and remote control and avoids the requirement of high photon energy for photochemistry. In this review, we discuss recent advances in photothermal LCE materials and investigate methods for mechanical alignment, external field alignment, and surface-induced alignment. Advances in the synthesis and orientation of LCEs have enabled liquid crystal elastomers to meet applications in optics, robotics, and more. The review concludes with a discussion of current challenges and research opportunities.