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The purpose of this study was first to examine and then to maximize, the adsorbency of torrefied barley straw, in order to remove basic dyes like Methylene Blue (MB) from wastewater. On the other hand, the effect of the torrefaction process on the heating value of the material was investigated. Moderate modification conditions (220 ºC, 20 min) were found to maximize adsorbency of modified barley straw. The experimental data were simulated by a pseudo-second order kinetic model. The torrefaction also significantly enhanced the higher heating value of the pretreated barley straw compared to the untreated material. Specifically, the calorific value increased from 16.1 MJ/kg to 19.4 MJ/kg for sample torrefied at 240 ºC during 40 min. Consequently, the torrefaction of barley straw leads to the coproduction of material with enhanced energy content in combination with improved adsorption capacity. The coproduction of energy and adsorbents from lignocellulosic biomass takes into account (i) the biorefinery (more than one product) and (ii) the Industrial Ecology concept (using solid waste to clean wastewater pollution).