In the literature devoted to magnetic impurities in Dirac semimetals, the appearance of anisotropic and long-range non-oscillating contributions to the Ruderman–Kittel–Kasuya–Yosida interaction is predicted. These contributions are due to the hybridization of the wave functions of magnetic impurities with the wave functions of Dirac electrons, which have a linear dispersion law. We have studied electron paramagnetic resonance (EPR) in powder samples of topological 3D Dirac semimetal Cd3As2 with an admixture of chromium ions. Anisotropy of the magnetic susceptibility in the paramagnetic state was found from the behavior of the resonance field. The appearance of magnetic anisotropy in the paramagnetic state is associated with an increase in the contribution of the orbital moments of chromium ions Cr2+ and Cr3+ due to their interaction with the orbital moments of donor Dirac electrons, which have anomalously large values of g factors.

The behavior of the manganese impurity in the 3D Dirac semimetal Cd3As2 has been studied by EPR and electromagnetic measurements. It was found that, in contrast to doping with europium, doping with manganese, as well as with iron, does not lead to a change in the sign of the magnetoresistance, which is almost completely suppressed at high manganese concentrations. In this case, a change in the type of the influence of the magnetic field on the contact potential is manifested. The g-factors measured in EPR coincide with the g-factor of a free electron at all temperatures, which, taking into account the fluctuation behavior of the EPR linewidth and the reduced magnetic moment on Mn2 +, indicates the formation of short-lived bound states of the Mn2 + ion and conduction electrons - antiferromagnetic polarons.