The paper presents the results of a study at room temperature of the quantization effect of the conductivity of memristive structures based on the organic material poly-p-xylylene with resistive switching. Measurement methods are shown and a comparative analysis of the manifestation of the effect when switching structures to a high-resistance and low-resistance state is carried out. The possibility of setting stable quantum states of conductivity in memristive structures based on poly-p-xylylene is demonstrated. It is shown that some of these states have short-term, and some long-term stability. The results obtained open up new possibilities for using the quantization effect of conductivity in the implementation of neuromorphic systems.