We present a numerical and experimental demonstration of a waveguide regime in a broad band spectral range for the hollow core microstructured optical fibers (HC MOFs) made of silica with a negative curvature of the core boundary. It is shown that HC MOFs with the cladding consisting only of one row of silica capillaries allows to guide light from the near to mid infrared despite of high material losses of silica in this spectral region. Such result can be obtained by a special arrangement of cladding capillaries which leads to a change in the sign of the core boundary curvature. The change in the sign of the core boundary curvature leads to a loss of simplicity of boundary conditions for core modes and to "localization" and limitation of their interaction with the cladding material in space. Such HC MOFs made of different materials can be potential candidates for solving problem of ultra high power transmission including transmission of CO and CO2 laser radiation.

In this paper we demonstrate the light transmission in a spectral range of 2.5 to 7.9 µm through a silica negative curvature hollow core fiber (NCHCF) with a cladding consisting of eight capillaries. A separation between the cladding capillaries was introduced to remove the additional resonances in the transmission bands. The measured optical loss at 3.39 µm was about 50 dB/km under a few modes waveguide regime.

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A technologically simple optical fiber cross-section structure with a negative-curvature hollow-core has been proposed for the delivery of the CO2 laser radiation. The structure was optimized numerically and then realized using Te20As30Se50 (TAS) chalcogenide glass. Guidance of the 10.6 µm СО2-laser radiation through this TAS-glass hollow-core fiber has been demonstrated. The loss at λ=10.6 μm was amounted ~11 dB/m. A resonance behavior of the fiber bend loss as a function of the bend radius has been revealed.

Interstitial negative-charged bismuth dimers, Bi(-)(2) and Bi(2-)(2), are suggested as a model of broadband IR luminescence centers in bismuth-doped glasses. The model is based on quantum-chemical calculations of equilibrium configurations, absorption, luminescence, and luminescence excitation spectra of the dimers in an alumosilicate network and is supported by IR luminescence observed for the first time, to our knowledge, in bismuth-doped polycrystalline magnesium cordierite.