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Graphical abstractNew cationic heteroleptic Ln(III) complexes with acetylacetonate and bis(5-(pyridine-2-yl)-1,2,4-triazol-3-yl)propane basis are synthesized. The complexes are characterized by various means, including single crystal X-ray diffraction analysis. Electronic absorption and emission spectra of the compounds both in solid and solutions are studied.

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New bi- and trinuclear copper(ii) complexes of aroylhydrazones of TFA and benzenecarboxylic acids were synthesized and characterized. Despite long range intramolecular CuCu distances of about 10 Å, exchange couplings between paramagnetic centres are observed with J values of 0.33 and 0.37 cm(-1) in binuclear complexes, and -0.33 cm(-1) in trinuclear complexes. Seven hyperfine peaks with a value of aCu = 37.0 × 10(-4) cm(-1) are observed in EPR spectra of binuclear complexes. The possible mechanisms responsible for the observed weak long range coupling via aromatic spacers are discussed.

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