Back Cover: The growth mechanism was clarified and differences between the plasma‐ and neutral gas‐grown carbon nanotubes were explained by using an enhanced large‐scale model and numerical simulation technique. The nanotubes synthesized by plasma process can be longer than those synthesized by neutral gas technique. The low‐temperature growth of the nanotube array is also possible when the hydrocarbon ion flux to the nanotubes dominates over fluxes of other species. Further details can be found in the article Gennady Burmaka et al. http://doi.wiley.com/10.1002/ppap.201400059.

The enhanced large‐scale model and numerical simulations are used to clarify the growth mechanism and the differences between the plasma‐ and neutral gas‐grown carbon nanotubes, and to reveal the underlying physics and the key growth parameters. The results show that the nanotubes grown by plasma can be longer due to the effects of hydrocarbon ions with velocities aligned with the nanotubes. We show that the low‐temperature growth is possible when the hydrocarbon ion flux dominates over fluxes of other species. We have also analysed the dependencies of the nanotube growth rates on nanotube and process parameters. The results are verified by a direct comparison with the experimental data. The model is generic and can be used for other types of carbon nanostructures such as carbon nanowalls, vertical graphenes, etc.

A zero-dimensional, space-averaged model for argon plasma afterglow with large dust density is developed. In the model, three groups of electrons in the plasma afterglow are assumed: (i) thermal electrons with Maxwellian distribution, (ii) energetic electrons generated by metastable-metastable collisions (metastable pooling), and (iii) secondary electrons generated at collisions of ions with the electrodes, which have sufficiently large negative voltages in the afterglow. The model calculates the time-dependencies for electron densities in plasma afterglow based on experimental decay times for metastable density and electrode bias. The effect of secondary emission on electron density in the afterglow is estimated by varying secondary emission yields. It is found that this effect is less important than metastable pooling. The case of dust-free plasma afterglow is considered also, and it is found that in the afterglow the effect of secondary emission may be more important than metastable pooling. The secondary emission may increase thermal electron density ne in dust-free and dusty plasma afterglows on a few ten percentages. The calculated time dependencies for ne in dust-free and dusty plasma afterglows describe well the experimental results.

It is studied how dissociation and ionization of acetylene molecules in their collisions with argon atoms in excited states Ar* may affect properties of argon-acetylene plasma with growing inside of plasma volume dust particles. The study is carried out using a volume-averaged model. To analyze the effects of Ar* atoms on the electron and ion densities, the effective electron temperature and the densities of radical and nonradical neutral species, the values of ionization and dissociation rates for collisions of acetylene molecules with Ar* atoms are varied in numerical calculations. It is found that the collisions of Ar* atoms with acetylene molecules affect essentially the argon-acetylene dusty plasma.