We study possibility of efficient reflection of very cold neutrons (VCN) from powders of nanoparticles. In particular, we measured the scattering of VCN at a powder of diamond nanoparticles as a function of powder sample thickness, neutron velocity and scattering angle. We observed extremely intense scattering of VCN even off thin powder samples. This agrees qualitatively with the model of independent nanoparticles at rest. We show that this intense scattering would allow us to use nanoparticle powders very efficiently as the very first reflectors for neutrons with energies within a complete VCN range up to $10^{-4}$ eV

We studied the phenomenon of relatively small changes in the energy of ultracold neutrons (UCN) (when compared to thermal motion energy) when these are reflected on a surface. The changes observed involved both increases in UCN energy (their heating) and decreases (cooling) of the order of ~ 10-7 eV. The probability values of this process on various surfaces ranged between 10-8 and 10-5 per one collision; the probability of such a small heating was many times larger than that of such a small cooling. We measured the spectra of such heated neutrons and the dependence of small heating probability on the temperature of sample out-gazing. We found that out-gazing of samples in vacuum at a temperature of 500–600 K could increase the small heating probability on stainless steel surface by a factor of ~ 100; and on copper surface by a factor of ~ 10. We observed, for the first time, extremely intensive small heating of UCN on powder of diamond nanoparticles. Neither small heating of UCN, nor nanoparticles could be found on a sapphire single crystal surface. This set of experimental data indicates that the inelastic scattering of UCN on weakly bound nanoparticles at a surface in a state of thermal motion is responsible for the process investigated.

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We report on storage of Very Cold Neutrons (VCN) in a trap with walls containing powder of diamond nanoparticles. The efficient VCN reflection is provided by multiple diffusive elastic scattering of VCN at single nanoparticles in powder. The VCN storage times are sufficiently long for accumulating large density of neutrons with complete VCN energy range of up to a few times 10(-4) eV. Methods for further improvements of VCN storage times are discussed

If the wavelength of radiation and the size of inhomogeneities in the medium are approximately equal, the radiation might be intensively scattered in the medium and reflected from its surface. Such efficient nanomaterial reflectors are of great scientific and technological interest. In previous works, we demonstrated a significant improvement in the efficiency of reflection of slow neutrons from a powder of diamond nanoparticles by replacing hydrogen located on the surface of nanoparticles with fluorine and removing the residual sp2 amorphous shells of nanoparticles via the fluorination process. In this paper, we study the mechanism of this improvement using a set of complementary experimental techniques. To analyze the data on a small-angle scattering of neutrons and X-rays in powders of diamond nanoparticles, we have developed a model of discrete-size diamond nanospheres. Our results show that fluorination does not destroy either the crystalline cores of nanoparticles or their clustering in the scale range of 0.6–200 nm. This observation implies that it does not significantly affect the neutron scattering properties of the powder. We conclude that the overall increase in reflectivity from the fluorinated nanodiamond powder is primarily due to the large reduction of neutron losses in the powder caused by the removal of hydrogen contaminations.