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A new type of intramolecular cyclization of 1,5 bis[2 (E 3 oxo 3 phenylprop 1 enyl) phenoxy] 3 oxapentane with 3 aminotriazole promoted by potassium ions was discovered. A cascade mechanism for the formation of crownophane with 4,7 dihydro[1,2,4]triazolo[1,5 a] pyrimidine fragment was suggested. Effects of oligooxyethylene fragment of the chalcone podand and acid base catalysis on the selectivity of the cyclocondensation processes and degree of oxidation of triazolopyrimidine fragments were studied. The product structures were confirmed by IR, 1 H and 13 C NMR spectroscopy and X ray diffraction study.

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